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Key Documents

209651

Sigma-Aldrich

Selenium

powder, −100 mesh, ≥99.5% trace metals basis

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About This Item

Empirical Formula (Hill Notation):
Se
CAS Number:
Molecular Weight:
78.96
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.23

description

gray

Quality Level

Assay

≥99.5% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: selenium

resistivity

1.2 μΩ-cm, 0°C

particle size

−100 mesh

bp

684.9 °C (lit.)

mp

217 °C (lit.)

density

4.81 g/mL at 25 °C (lit.)

SMILES string

[Se]

InChI

1S/Se

InChI key

BUGBHKTXTAQXES-UHFFFAOYSA-N

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General description

Selenium powder is a fine, powdery substance made up of small particles of the element selenium, often produced by the reduction of selenium oxide. Selenium powder is grey or silvered-colored and may have a metallic sheen that may appear reddish in color. This product is passed through a 100-mesh sieve, indicating that the particles are small and have a diameter of around 150 micrometers or less, and ensuring the powder is fine and easy-to-handle.

Application

Se is used in the synthesis of CdSe, which is consequetively used to modulate the photoresponse of quantum dot solar cells by varying the size and shape of semiconductor nanostructures.

Pictograms

Skull and crossbonesHealth hazard

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 4 - STOT RE 2

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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István Robel et al.
Journal of the American Chemical Society, 128(7), 2385-2393 (2006-02-16)
By using bifunctional surface modifiers (SH-R-COOH), CdSe quantum dots (QDs) have been assembled onto mesoscopic TiO(2) films. Upon visible light excitation, CdSe QDs inject electrons into TiO(2) nanocrystallites. Femtosecond transient absorption as well as emission quenching experiments confirm the injection
Daniel D Karp et al.
Journal of clinical oncology : official journal of the American Society of Clinical Oncology, 31(33), 4179-4187 (2013-09-05)
Selenium has been reported to have chemopreventive benefits in lung cancer. We conducted a double-blind, placebo-controlled trial to evaluate the incidence of second primary tumors (SPTs) in patients with resected non-small-cell lung cancer (NSCLC) receiving selenium supplementation. Patients with completely
Waleed Alhazzani et al.
Critical care medicine, 41(6), 1555-1564 (2013-04-17)
Patients with sepsis syndrome commonly have low serum selenium levels. Several randomized controlled trials have examined the efficacy of selenium supplementation on mortality in patients with sepsis. To determine the efficacy and safety of high-dose selenium supplementation compared to placebo
Claire M Weekley et al.
Nutrients, 5(5), 1734-1756 (2013-05-24)
Determining the speciation of selenium in vivo is crucial to understanding the biological activity of this essential element, which is a popular dietary supplement due to its anti-cancer properties. Hyphenated techniques that combine separation and detection methods are traditionally and
Kai-Oliver Feldmann et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(27), 9697-9712 (2015-05-12)
Although a fairly large number of binary group 15/16 element cations have been reported, no example involving phosphorus in combination with a group 16 element has been synthesized and characterized to date. In this contribution is reported the synthesis and structural characterization

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