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N8505

Sigma-Aldrich

乙酸-1-萘酯

≥98% (C)

别名:

乙酸-α-萘酯

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About This Item

线性分子式:
CH3CO2C10H7
CAS号:
830-81-9
分子量:
186.21
Beilstein:
2046403
EC號碼:
212-599-8
MDL號碼:
MFCD00003922
分類程式碼代碼:
12352202
PubChem物質ID:
24897679
NACRES:
NA.77

品質等級

200

化驗

≥98% (C)

形狀

crystals

mp

43-46 °C (lit.)

儲存溫度

−20°C

SMILES 字串

CC(=O)Oc1cccc2ccccc12

InChI

1S/C12H10O2/c1-9(13)14-12-8-4-6-10-5-2-3-7-11(10)12/h2-8H,1H3

InChI 密鑰

VGKONPUVOVVNSU-UHFFFAOYSA-N

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一般說明

1-乙酸萘酯是一种 1-萘酯。采用稳态光解和激光闪光光解研究了乙酸 1-萘酯的光 Fries 重排反应机理。用稳态、时间分辨化学诱导动态核极化 (CIDNP) 和闪光光解方法研究了乙酸萘酯的光 Fries 重排反应动力学。

應用

乙酸 1-萘酯可用于巨噬细胞的快速染色鉴定；通过更复杂的形态学标准、吞噬作用和 Fc 受体的存在证实了该方法的计数。它可能被用作研究非特异性羧酸酯酶 (EC 3.1.1) 在鲈鱼消化道中分布的底物。

象形圖

Corrosion
GHS05

訊號詞

Danger

危險聲明

H318

危險分類

Eye Dam. 1

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

235.4 °F

閃點（°C）

113 °C

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Laser flash photolysis and CIDNP studies of 1-naphthyl acetate photo-Fries rearrangement.
Gritsan NP, et al.
The Journal of Physical Chemistry, 100(11), 4448-4458 (1996)
Non-specific carboxylic esterase activity in the digestive tract of the perch, Perca fluviatilis L.
Hirji KN and Courtney WAM.
Journal of Fish Biology, 22(1), 1-7 (1983)
E F Barth et al.
Brazilian journal of biology = Revista brasleira de biologia, 78(4), 601-608 (2018-01-11)
This work describes the preliminary evaluation of cytotoxic, antimicrobial, molluscicidal, antioxidant and anticholinesterase activities from leaf (LECF) and stem bark alcoholic extracts (BECF) of the species Croton floribundus Spreng. (Euphorbiaceae), popularly known as capixingui or tapixingui. BECF presented significant toxicity
Magnetic isotope and external magnetic field effects upon the photo-Fries rearrangement of 1-naphthyl acetate.
Nakagaki R, et al.
The Journal of Physical Chemistry, 89(15), 3222-3226 (1985)
Zhuo Ma et al.
PloS one, 12(12), e0189343-e0189343 (2017-12-12)
Imidacloprid is a neonicotinoid insecticide that is effective against house fly, Musca domestica L., which is a major pest with the ability to develop resistance to insecticides. In the present study, we investigated the inheritance mode, the cross-resistance pattern and
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Fries Rearrangement

The Fries rearrangement reaction is an organic name reaction which involves the conversion of phenolic esters into hydroxyaryl ketones on heating in the presence of a catalyst. Suitable catalysts for this reaction are Brønsted or Lewis acids such as HF, AlCl3, BF3, TiCl4, or SnCl4. The Fries rearrangement reaction is an ortho, para-selective reaction, and is used in the preparation of acyl phenols. This organic reaction has been named after German chemist Karl Theophil Fries.

Fries Rearrangement

The Fries rearrangement reaction is an organic name reaction which involves the conversion of phenolic esters into hydroxyaryl ketones on heating in the presence of a catalyst. Suitable catalysts for this reaction are Brønsted or Lewis acids such as HF, AlCl3, BF3, TiCl4, or SnCl4. The Fries rearrangement reaction is an ortho, para-selective reaction, and is used in the preparation of acyl phenols. This organic reaction has been named after German chemist Karl Theophil Fries.

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