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Merck

270423

Sigma-Aldrich

硝基甲烷

suitable for HPLC, ≥96%

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About This Item

经验公式(希尔记法):
CH3NO2
CAS号:
分子量:
61.04
Beilstein:
1698205
EC號碼:
MDL號碼:
分類程式碼代碼:
12190000
PubChem物質ID:
NACRES:
NA.21
bp:
101.2 °C (lit.)

等級

HPLC grade

蒸汽密度

2.1 (vs air)

蒸汽壓力

2.7 mmHg

化驗

≥96%

形狀

liquid

自燃溫度

784 °F

expl. lim.

7.3 %, 33 °F

技術

HPLC: suitable

雜質

<0.030% water

折射率

n20/D 1.382 (lit.)

pH值

6.4 (20 °C, 0.01 g/L)

bp

101.2 °C (lit.)

mp

−29 °C (lit.)

密度

1.127 g/mL at 25 °C (lit.)

&lambda ;

H2O reference

紫外吸收

λ: 380 nm Amax: 1.00
λ: 386 nm Amax: 0.50
λ: 395 nm Amax: 0.20
λ: 400 nm Amax: 0.10
λ: 405 nm Amax: 0.05
λ: 430-700 nm Amax: 0.01

應用

food and beverages

SMILES 字串

C[N+]([O-])=O

InChI

1S/CH3NO2/c1-2(3)4/h1H3

InChI 密鑰

LYGJENNIWJXYER-UHFFFAOYSA-N

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應用


  • Asymmetric aza-Henry reaction toward trifluoromethyl β-nitroamines and biological investigation of their adamantane-type derivatives.: This study used nitromethane in asymmetric aza-Henry reactions to synthesize trifluoromethyl β-nitroamines, which were further investigated for their biological properties, showcasing the potential of nitromethane in advanced synthetic chemistry (Ren et al., 2024).

  • Effect of Temperature on the Liquid Bridging Force while Maintaining Physical Stability in Solid-Liquid Mixed Fuel.: Nitromethane was analyzed in this research to understand its role in the stability of solid-liquid mixed fuels under varying temperatures, providing insights into the optimization of fuel formulations (Zhang et al., 2024).

  • Generation of New Synthons for Synthesis Through Activation of Nitromethane.: This research demonstrated the activation of nitromethane to generate new synthons for synthetic applications, highlighting its versatility and importance in creating novel chemical entities (Wang et al., 2024).

  • Towards Chemoenzymatic Syntheses of Both Enantiomers of Phosphoemeriamine.: The study explored the use of nitromethane in chemoenzymatic syntheses, enabling the production of both enantiomers of phosphoemeriamine, an important compound in chemical biology (Kiełbasiński et al., 2024).

  • Rationally introducing non-canonical amino acids to enhance catalytic activity of LmrR for Henry reaction.: Nitromethane was employed in this study to investigate the enhancement of catalytic activity in the Henry reaction through the introduction of non-canonical amino acids, demonstrating its significance in enzyme catalysis research (Wang et al., 2024).

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訊號詞

Warning

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 3 - Repr. 2

儲存類別代碼

4.1A - Other explosive hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

95.0 °F - closed cup

閃點(°C)

35 °C - closed cup


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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The catalytic chemistry of nitromethane over Co-ZSM5 and other catalysts in connection with the methane-NOxSCR reaction.
Cowan AD, et al.
J. Catal., 176(2), 329-343 (1998)
Metal ion encapsulation: cobalt cages derived from polyamines, formaldehyde, and nitromethane.
Geue RJ, et al.
Journal of the American Chemical Society, 106(19), 5478-5488 (1984)
Benedek Vakulya et al.
Organic letters, 7(10), 1967-1969 (2005-05-07)
Cinchona alkaloid-derived chiral bifunctional thiourea organocatalysts were synthesized and applied in the Michael addition between nitromethane and chalcones with high ee and chemical yields.
Atanu Bhattacharya et al.
The Journal of chemical physics, 136(2), 024321-024321 (2012-01-21)
Decomposition of electronically excited nitro-containing molecules with different X-NO(2) (X = C, N, O) moieties has been intensively investigated over the past decades; however, their decomposition behavior has not previously been compared and contrasted. Comparison of their unimolecular decomposition behavior
Eagleson M.
Concise Encyclopedia Chemistry, 696-696 (1994)

实验方案

GC Analysis of Class 2 Residual Solvents on OVI-G43

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