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蒸汽壓力
50 mmHg ( 55 °C)
9.6 mmHg ( 20 °C)
品質等級
化驗
≥99.995% trace metals basis
形狀
liquid
liquid
反應適用性
reagent type: catalyst
core: titanium
bp
135-136 °C (lit.)
136.4 °C
mp
−25 °C (lit.)
密度
1.73 g/mL at 20 °C (lit.)
SMILES 字串
Cl[Ti](Cl)(Cl)Cl
InChI
1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
InChI 密鑰
XJDNKRIXUMDJCW-UHFFFAOYSA-J
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一般說明
Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone. Neutral solutions of TiCl4 having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) are used to synthesize nanosized titanium dioxide.
應用
促进 (S)-2-苄氧-3-戊酮在 THF 或 DME 中的高选择性羟醛缩合反应。
活化四氢吡咯以提高通过修正的波沃反应转化成相应的 α,α-二甲胺的转化率。
Titanium(IV) chloride has been used in the synthesis of anatase TiO2 structures with macropores (250nm in diameter) and mesoscale pores (50nm in diameter).
訊號詞
Danger
危險聲明
危險分類
Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
標靶器官
Respiratory system
安全危害
儲存類別代碼
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
水污染物質分類（WGK）
WGK 1
閃點（°F）
Not applicable
閃點（°C）
Not applicable
其他客户在看
Victor Rodríguez-Cisterna et al.
The Journal of organic chemistry, 72(17), 6631-6633 (2007-07-20)
Stereoselectivity of TiCl4-mediated aldol reactions from (S)-2-benzyloxy-3-pentanone is dramatically improved when the reaction is carried out in the presence of 1.1 equiv of tetrahydrofuran (THF) or 1,2-dimethoxyethane (DME). The resultant 2,4-syn-4,5-syn adducts are then obtained in diastereomeric ratios up to
A Review of Mesoporous TiO2 Thin Films
Wang J, et al.
Material Matters, 7(2) null
Precipitation of nanosized titanium dioxide from aqueous titanium (IV) chloride solutions by neutralization with MgO.
Li Y and Demopoulos GP.
Hydrometallurgy, 90(1), 26-33 (2008)
Denton, S.M. Wood, A.
Synlett, 55-55 (1999)
Soji Shimizu et al.
Chemical communications (Cambridge, England), 49(16), 1621-1623 (2013-01-23)
Pyrrolopyrrole aza-BODIPY analogues were synthesized from diketopyrrolopyrrole and heteroaromatic amines in the presence of titanium tetrachloride. These novel compounds exhibit intense absorption in the visible region and strong emission with high fluorescence quantum yields greater than 0.8.
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