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Merck

244120

Sigma-Aldrich

过硼酸钠 四水合物

9-11% available Oxygen

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About This Item

线性分子式:
NaBO3 · 4H2O
CAS号:
分子量:
153.86
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.55

形狀

powder or granules

品質等級

品質

9-11% available Oxygen

濃度

~6.5-7.5% NaOH (titration)
~9-11% (active oxygen basis (by Na2S2O3, titration))

pH值

10-10.4 (25 °C, 10 g/L)

mp

60 °C (dec.) (lit.)

SMILES 字串

O.O.O.O.[Na+].[O-]B1OO1

InChI

1S/BO3.Na.4H2O/c2-1-3-4-1;;;;;/h;;4*1H2/q-1;+1;;;;

InChI 密鑰

IBDSNZLUHYKHQP-UHFFFAOYSA-N

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一般說明

Sodium perborate is widely employed as an oxidizing agent.

應用

Sodium perborate tetrahydrate may be employed for the following studies:
  • Transformation of iodoarenes to (diacetoxyiodo)arenes.
  • Oxidation of Π-deficient azines to afford N-oxides.
  • Oxidation of sulphur containing heterocyclic compounds to afford S,S-dioxides.
  • Microwave-assisted oxidative hydration of various aromatic and aliphatic nitriles.
  • Various oxidation reactions of anilines and sulphides.
  • As a catalyst for the transformation of 2′-hydroxychalcones to flavanones.

訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 1B - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Sodium perborate tetrahydrate?mediated transformations of 2'-hydroxychalcones to flavanones, flavones, and 3', 5'-diiodoflavone under mild, environmentally friendly conditions.
Ganguly NC, et al.
Synthetic Communications, 43(10), 1351-1361 (2013)
Further functional group oxidations using sodium perborate.
McKillop A and Kemp D.
Tetrahedron, 45(11), 3299-3306 (1989)
Functional group oxidation using sodium perborate1.
McKillop A and Tarbin JA.
Tetrahedron, 43(8), 1753-1758 (1987)
Microwave-promoted transformation of nitriles to amides with aqueous sodium perborate.
Sharifi A, et al.
Synthetic Communications, 31(3), 431-434 (2001)
Gabriella Simbula et al.
Journal of endodontics, 36(9), 1516-1520 (2010-08-24)
Tetraacetylethylenediamine in association with sodium perborate (TAED+P) can be suggested for its use as an endodontic disinfectant because of its antimicrobial activity against different bacterial species when used at low concentrations. The purpose of this study was to measure the

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