推荐产品
蒸汽壓力
1 hPa ( 748 °C)
產品線
ReagentPlus®
化驗
≥99%
形狀
powder
pH值
7 (20 °C, 10 g/L)
mp
550 °C (lit.)
SMILES 字串
[Li+].[Br-]
InChI
1S/BrH.Li/h1H;/q;+1/p-1
InChI 密鑰
AMXOYNBUYSYVKV-UHFFFAOYSA-M
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一般說明
LiBr/三甲基氯硅烷试剂参与醇向溴化物的转换。
應用
溴化锂（LiBr）可用作以下研究的催化剂：
- 通过无溶剂二硫代缩醛反应将（芳族-和α,β-不饱和）醛转化为二硫代缩醛。
- 通过羰基化合物与活性亚甲基化合物的缩合反应合成烯烃。
- β-氨基醇的绿色合成。
- 通过使用LiBr/硝酸铈铵（CAN）试剂系统（作为Br+ 离子来源）进行芳族化合物的化学和区域选择性溴化。
法律資訊
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Redi-Dri is a trademark of Sigma-Aldrich Co. LLC
訊號詞
Warning
危險分類
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1
儲存類別代碼
13 - Non Combustible Solids
水污染物質分類（WGK）
WGK 1
閃點（°F）
Not applicable
閃點（°C）
Not applicable
其他客户在看
Lithium Bromide, an Inexpensive and Efficient Catalyst for Opening of Epoxide Rings by Amines at Room Temperature under Solvent-Free Condition.
Chakraborti AK, et al.
European Journal of Organic Chemistry, 2004(17), 3597-3600 (2004)
An efficient chemo and regioselective oxidative nuclear bromination of activated aromatic compounds using lithium bromide and ceric ammonium nitrate.
Roy SC, et al.
Tetrahedron Letters, 42(39), 6941-6942 (2001)
Lithium bromide-catalyzed highly chemoselective and efficient dithioacetalization of α,β-unsaturated and aromatic aldehydes under solvent-free conditions.
Firouzabadi H, et al.
Synthesis, 58-60 (1999)
Lithium bromide as a new catalyst for carbon-carbon bond formation in the solid state.
Prajapati D, et al.
Journal of the Chemical Society. Perkin Transactions 1, 9, 959-960 (1996)
R Quaderer et al.
Organic letters, 3(20), 3181-3184 (2001-09-28)
[reaction: see text] The alkanesulfonamide "safety-catch" resin has proven useful for Fmoc-based synthesis of C-terminal peptide thioesters. We now report that the yield of isolated thioester can increase significantly when the cleavage reaction is carried out in 2 M LiBr/THF
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