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Merck

73594

Supelco

乙酸铵

LiChropur, eluent additive for LC-MS

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About This Item

线性分子式:
CH3CO2NH4
CAS号:
分子量:
77.08
Beilstein:
4186741
EC號碼:
MDL號碼:
分類程式碼代碼:
12000000
eCl@ss:
39021908
PubChem物質ID:
NACRES:
NB.21

等級

eluent additive for LC-MS

品質等級

agency

suitable for ASTM® 7968
suitable for ASTM® 7979
suitable for DIN 38407-42
suitable for EPA 1633
suitable for EPA 533
suitable for EPA 537.1
suitable for EPA 8327
suitable for EPA ACB B21-02
suitable for EPA ACB B23-05b
suitable for GB 31604.35-2016
suitable for GB 5009.253-2016
suitable for ISO 21675 2019
suitable for ISO 25101
suitable for ISO/CEN 15968-2010

法律遵循

suitable for FDA C-010.02

化驗

≥99.0% (calc. on dry substance, T)

形狀

solid

品質

LiChropur

技術

LC/MS: suitable

雜質

insoluble matter, passes filter test
≤1% water

燃燒殘留物

≤0.01% (as SO4)

pH值

6.2-7.5 (25 °C, 1 M in H2O)

mp

110-112 °C (dec.) (lit.)

溶解度

H2O: 1 M at 20 °C, clear, colorless

負離子痕跡

chloride (Cl-): ≤5 mg/kg
nitrate (NO3-): ≤10 mg/kg
sulfate (SO42-): ≤10 mg/kg

正離子痕跡

Al: ≤1 mg/kg
As: ≤0.1 mg/kg
Ba: ≤1 mg/kg
Bi: ≤1 mg/kg
Ca: ≤5 mg/kg
Cd: ≤1 mg/kg
Co: ≤1 mg/kg
Cr: ≤1 mg/kg
Cu: ≤1 mg/kg
Fe: ≤1 mg/kg
K: ≤5 mg/kg
Li: ≤1 mg/kg
Mg: ≤1 mg/kg
Mn: ≤1 mg/kg
Mo: ≤1 mg/kg
Na: ≤5 mg/kg
Ni: ≤1 mg/kg
Pb: ≤1 mg/kg
Sr: ≤1 mg/kg
Zn: ≤1 mg/kg

SMILES 字串

N.CC(O)=O

&lambda ;

1 M in H2O

紫外吸收

λ: 260 nm Amax: ≤0.015
λ: 280 nm Amax: ≤0.010

適合性

passes test for LC-MS

InChI

1S/C2H4O2.H3N/c1-2(3)4;/h1H3,(H,3,4);1H3

InChI 密鑰

USFZMSVCRYTOJT-UHFFFAOYSA-N

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一般說明

乙酸铵以白色晶体的形式存在。它时以醋酸和氨为原料制备,经中和至pH 7.0。 它被广泛应用于分析化学、医药、纺织染色等领域。

應用

乙酸铵已可用于制备UPLC-MS/MS洗脱液和HPLC-MS/MS洗脱液,以比较9种药物化合物在水环境样品中的基质效应。它还被用作添加剂,以提高MALDI-MS对磷酸肽的检测。

推薦產品

探索最适于HPLCLC-MS分析的LiChropur试剂

法律資訊

ASTM is a registered trademark of American Society for Testing and Materials
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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Enhanced detection of phosphopeptides in matrix-assisted laser desorption/ionization mass spectrometry using ammonium salts.
Asara JM, Allison J.
Journal of the American Society For Mass Spectrometry, 10(1), 35-44 (1999)
Comparison of matrix effects in HPLC-MS/MS and UPLC-MS/MS analysis of nine basic pharmaceuticals in surface waters.
Van De Steene JC, Lambert WE.
Journal of the American Society For Mass Spectrometry, 19(5), 713-718 (2008)
Dale L. Perry
Handbook of Inorganic Compounds, 17-17 (1995)
J M Asara et al.
Journal of the American Society for Mass Spectrometry, 10(1), 35-44 (1999-01-15)
Matrix-assisted laser desorption/ionization mass spectrometry (MALDI MS) has been used successfully to detect phosphorylation sites in proteins. Applications may be limited by the low response of phosphopeptides compared to nonphosphorylated peptides in MALDI MS. The addition of ammonium salts to
Jet C Van De Steene et al.
Journal of the American Society for Mass Spectrometry, 19(5), 713-718 (2008-03-18)
When developing an LC-MS/MS-method matrix effects are a major issue. The effect of co-eluting compounds arising from the matrix can result in signal enhancement or suppression. During method development much attention should be paid to diminishing matrix effects as much

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