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44920

Sigma-Aldrich

乙酰丙酮铁 III

purum, ≥97.0% (RT)

别名:

2,4-戊二酮 铁(III) 衍生物, 2，4-戊二酮铁（III）, Fe(acac)3, 乙酰丙酮铁

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About This Item

线性分子式:
Fe(C5H7O2)3
CAS号:
14024-18-1
分子量:
353.17
Beilstein:
4157960
EC號碼:
237-853-5
MDL號碼:
MFCD00000020
分類程式碼代碼:
12352103
PubChem物質ID:
329756564
NACRES:
NA.23

等級

purum

品質等級

200

化驗

≥97.0% (RT)

形狀

powder

反應適用性

core: iron
reagent type: catalyst

mp

180-182 °C (dec.) (lit.)
180-190 °C (dec.)

密度

5.24 g/mL at 25 °C (lit.)

SMILES 字串

CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI 密鑰

AQBLLJNPHDIAPN-LNTINUHCSA-K

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相关类别

一般說明

Iron(III) acetylacetonate, also known as tris(acetylacetonato)iron(III) or Fe(acac)3, is a coordination compound that is highly soluble in organic solvents. It is used as a precursor in the preparation of iron-containing materials and thin films, which are important in electronics and coatings. Additionally, it is also as a catalyst in organic reactions, particularly in the synthesis of organic compounds and polymerization processes.

應用

用于高结晶（Zn，Fe）Fe2O4 薄膜的 MOCVD 前体和这些薄膜的磁性测量。
Iron(III) acetylacetonate can be used as:     
  • A precursor in the synthesis of Fe3O4/carbon composite fibers via forcespinning. This fiber material is suitable for use as anode materials in lithium-ion batteries.     
  • A precursor in the synthesis of iron-based metal-organic frameworks (MOFs) for the applications in rechargeable alkali-ion batteries.
  • A catalyst in the controlled living radical polymerization of vinyl acetate to synthesis of polymers with controlled molecular weights.   
  • A precursor to synthesize iron-doped titania (Fe-TiO2) photocatalysts for the potential applications in photocatalytic reactions.     
  • A MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.

其他說明

用于格氏反应的催化剂，添加酸性氯化物可生成酮。

象形圖

CorrosionExclamation mark
GHS05,GHS07

訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCB3470
BCBV4183
BCBT5666
BCBS5090V
BCBR4648V

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V. Fiandanese et al.
Tetrahedron Letters, 25, 4805-4805 (1984)
C. Cardellicchio et al.
Tetrahedron Letters, 28, 2053-2053 (1987)
Roland Schoch et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 15(17), 3768-3775 (2014-09-13)
A new iron-based catalyst for carbon monoxide oxidation, as a potential substitute for precious-metal systems, has been prepared by using a facile impregnation method with iron tris-acetylacetonate as a precursor on γ-Al2 O3 . Light-off and full conversion temperatures as
Tingting Li et al.
Nanoscale, 7(9), 4171-4178 (2015-02-12)
The excellent electrochemical performance of greigite (Fe3S4) coupled with its vast abundance and low toxicity make it a good prospect as an anode material for lithium ion batteries (LIBs). In this research, a simple and feasible approach for producing pure
Michael Challenor et al.
Dalton transactions (Cambridge, England : 2003), 43(44), 16780-16787 (2014-10-07)
We report the synthesis, characterisation and evaluation of the in vitro biocompatibility of polymeric nanoparticles with both magnetic and upconverting fluorescent properties. The particles consist of superparamagnetic iron oxide nanoparticles and upconverting NaYF4:Yb,Er nanoparticles co-encapsulated within a poly(glycidyl methacrylate) sphere.
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