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Merck

33120-M

Sigma-Aldrich

N,N-二甲基甲酰胺

puriss. p.a., ACS reagent, reag. Ph. Eur., ≥99.8% (GC)

别名:

DMF, NSC 5356

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About This Item

线性分子式:
HCON(CH3)2
CAS号:
分子量:
73.09
Beilstein:
605365
EC號碼:
MDL號碼:
分類程式碼代碼:
12352111
PubChem物質ID:
NACRES:
NA.21

等級

ACS reagent
puriss. p.a.

品質等級

agency

reag. Ph. Eur.

蒸汽密度

2.5 (vs air)

蒸汽壓力

2.7 mmHg ( 20 °C)

化驗

≥99.8% (GC)

形狀

liquid

自燃溫度

833 °F

expl. lim.

15.2 %

技術

cell culture | plant: suitable

雜質

≤0.001% non-volatile matter
≤0.003% free acid (as CH3COOH)
≤0.005% free alkali (as NH3)
≤0.1% water (Karl Fischer)

顏色

APHA: ≤15

折射率

n20/D 1.4290-1.4310
n20/D 1.430 (lit.)

pH值

6.7

bp

152-154 °C
153 °C (lit.)

mp

−61 °C (lit.)

密度

0.948-0.950 g/mL at 20 °C
0.944 g/mL (lit.)

正離子痕跡

Al: ≤0.5 mg/kg
B: ≤0.02 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.1 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.02 mg/kg
Cu: ≤0.02 mg/kg
Fe: ≤0.1 mg/kg
K: ≤0.5 mg/kg
Li: ≥0.1 mg/kg
Mg: ≤0.1 mg/kg
Mn: ≤0.02 mg/kg
Mo: ≤0.1 mg/kg
Na: ≤1 mg/kg
Ni: ≤0.02 mg/kg
Pb: ≤0.1 mg/kg
Sn: ≤0.1 mg/kg
Sr: ≤0.1 mg/kg
Zn: ≤0.1 mg/kg

SMILES 字串

[H]C(=O)N(C)C

InChI

1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3

InChI 密鑰

ZMXDDKWLCZADIW-UHFFFAOYSA-N

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一般說明

N,N-Dimethylformamide (DMF) is commonly employed as a solvent for various organic reactions. DMF is a useful solvent employed for the isolation of chlorophyll from plant tissues. It is widely employed reagent in organic synthesis. It plays multiple roles in various reactions such as solvent, dehydrating agent, reducing agent as well as catalyst. It is a multipurpose building block for the synthesis of compounds containing O, -CO, -NMe2, -CONMe2, -Me, -CHO as functional groups.

應用

N,N-Dimethylformamide (DMF) may be employed as a solvent in the following studies:
  • Extraction of chlorophyll containing pigments from the intact tissues of cotyledons of Cucumis sativus.
  • Isolation of chlorophyll a from the cell cultures of unicellular marine algae.4
  • As reducing agent and solvent for the preparation of Au@Ag core-shell nanocrystals.
多种疏水性有机化合物的溶剂。

包裝

2.5 L also available in PE-bottles

訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

136.4 °F - closed cup

閃點(°C)

58 °C - closed cup


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W P Inskeep et al.
Plant physiology, 77(2), 483-485 (1985-02-01)
We found inconsistencies in the commonly used data for chlorophyll analysis in 80% acetone. Recently developed extinction coefficients for chlorophyll b in N,N-dimethylformamide (DMF) based on values from 80% acetone are low as a result of these inconsistencies. We determined
Shengtao Ding et al.
Angewandte Chemie (International ed. in English), 51(37), 9226-9237 (2012-08-30)
Often used as a common solvent for chemical reations and utilized widely in industry as a reagent, N,N-dimethylformamide (DMF) has played an important role in organic synthesis for a long time. Numerous highly useful articles and reviews discussing its utilizations

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