03505

1,2-二溴乙烷

purum, ≥98.0% (GC)

• 别名: EDB, 二溴化乙烯
• 线性分子式: BrCH₂CH₂Br
• CAS号: 106-93-4
• 分子量: 187.86
• Beilstein: 605266
• EC號碼: 203-444-5
• MDL號碼: MFCD00000233
• 分類程式碼代碼: 12352100
• PubChem物質ID: 329747727
• NACRES: NA.22

属性

• 蒸汽密度: ~6.5 (vs air)
• 品質等級: 200
• 蒸汽壓力: 11.7 mmHg ( 25 °C)
• 等級: purum
• 化驗: ≥98.0% (GC)
• 形狀: liquid
• 折射率: n20/D 1.539 (lit.); n20/D 1.539
• bp: 131-132 °C (lit.)
• mp: 8-11 °C (lit.)
• 密度: 2.18 g/mL at 25 °C (lit.)
• SMILES 字串: BrCCBr
• InChI: 1S/C2H4Br2/c3-1-2-4/h1-2H2
• InChI 密鑰: PAAZPARNPHGIKF-UHFFFAOYSA-N

说明

一般說明

1,2-Dibromoethane (EDB) is a water-soluble dihaloalkane that was widely used as a soil and grain fumigant. This led to the contamination of soil, surface, and groundwater with residual EDB. As it is a potent carcinogen and mutagen, many studies have been conducted to identify chemical reactions for its degradation in the environment.

應用

1,2-Dibromoethane can be used:

• To generate vinyl bromide in situ, which can undergo a palladium-catalyzed cross-coupling reaction with aryl boronic acids to form functionalized styrene derivatives.
• As a brominating agent of tertiary carbanions in sterically hindered molecules.
• As a building block to synthesize 2-arylsulfonyl hydrazones, (±)-horsfiline and 7-oxo-2, 3-dihydro-7H-pyrido [1,2,3-de] [1,4] benzoxazine-6-carboxylic acids.

安全信息

• 象形圖: GHS06,GHS08,GHS09
• 訊號詞: Danger
• 危險聲明: H301 + H311 + H331 - H315 - H319 - H335 - H350 - H411
• 防範說明: P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338
• 危險分類: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Carc. 1B - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter