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Merck

02300

Sigma-Aldrich

D-(+)-苹果酸

unnatural form, ≥97.0% (T)

别名:

(R)-(+)-2-羟基琥珀酸, D-羟基丁二酸

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About This Item

线性分子式:
HO2CCH2CH(OH)CO2H
CAS号:
分子量:
134.09
Beilstein:
1723540
EC號碼:
MDL號碼:
分類程式碼代碼:
51113400
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥97.0% (T)

光學活性

[α]20/D +28.0±2°, c = 5.5% in pyridine

品質

unnatural form

mp

98-102 °C (lit.)

官能基

carboxylic acid
hydroxyl

SMILES 字串

O[C@H](CC(O)=O)C(O)=O

InChI

1S/C4H6O5/c5-2(4(8)9)1-3(6)7/h2,5H,1H2,(H,6,7)(H,8,9)/t2-/m1/s1

InChI 密鑰

BJEPYKJPYRNKOW-UWTATZPHSA-N

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應用

D-(+)-苹果酸可用于:
  • 作为对映选择性全合成 (−)-erinapyrone B的起始材料。
  • 作为从各种醛、苯胺和亚磷酸二乙酯合成α-氨基膦酸酯的手性有机催化剂。

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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分析证书(COA)

Lot/Batch Number

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访问文档库

One pot green synthesis of α-aminophosphonates with D-Malic acid as an organocatalyst
AIP Conference Proceedings, 1860(1), 020057-020057 (2017)
R Kaminsky et al.
Tropical medicine & international health : TM & IH, 1(2), 255-263 (1996-04-01)
The unique features of purine salvage systems of pathogenic haemoflagellates render them selectively susceptible to the cytotoxic effects of purine analogues. A series of acyclic nucleoside phosphonates were evaluated for activity against pathogenic haemoflagellates in vitro. One of the phosphonylmethoxyalkylpurines
Concise Total Synthesis of (-)-Erinapyrone B from D-(+)-Malic Acid
Samala R, et al.
Synthetic Communications, 44(4), 500-506 (2014)
M J Gómez-Lechón et al.
Hepatology (Baltimore, Md.), 23(5), 1012-1019 (1996-05-01)
Human hepatocytes stimulated with human recombinant hepatocyte growth factor (h-rHGF) (10 ng/mL) displayed a characteristic lag period before entering into the S phase. The duration of this delay was dependent on the timing of h-rHGF addition to cultures. The highest
C Orskov et al.
FEBS letters, 247(2), 193-196 (1989-04-24)
We developed specific, C-terminal radioimmunoassays for three proglucagon (PG) fragments: PG 151-158, PG 151-160 and PG 126-159 (glucagon-like peptide-2 (GLP-2] in order to determine the exact C-terminal sequence of the newly isolated GLP-2 in man and pig. The antigens and

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