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Merck

C409

Sigma-Aldrich

(1R,3S)-(+)-樟脑酸

99%

别名:

(+)-樟脑酸, (1R,3S)-1,2,2-三甲基-1,3-环戊烷二羧酸

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About This Item

经验公式(希尔记法):
C10H16O4
CAS号:
分子量:
200.23
Beilstein:
2050204
EC號碼:
MDL號碼:
分類程式碼代碼:
51113400
PubChem物質ID:
NACRES:
NA.22

化驗

99%

形狀

powder

光學活性

[α]20/D 46°, c = 1 in ethanol

mp

183-186 °C (lit.)

SMILES 字串

CC1(C)[C@H](CC[C@@]1(C)C(O)=O)C(O)=O

InChI

1S/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)/t6-,10+/m1/s1

InChI 密鑰

LSPHULWDVZXLIL-LDWIPMOCSA-N

一般說明

樟脑酸是一种二酸,一般通过萜烯(+)-樟脑氧化制备。它可用作一些有机反应中的手性诱导剂。

應用

(1R,3S)-(+)-樟脑酸可用于制备(1R,2S,3R,5S)-2,3-二苄基-1,8,8-三甲基-3-硫杂双环[3.2.1] 辛烷高氯酸盐。它与吡啶(py)或吡啶/甲醇(MeOH)中的硝酸铀酰反应形成新型铀酰-有机组合。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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