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ALD00610

2-(4-Chloro-6-methoxy-1,3,5-triazin-2-yl)benzonitrile

Name: 2-(4-Chloro-6-methoxy-1,3,5-triazin-2-yl)benzonitrile
Brand: ALDRICH

≥95%

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About This Item

经验公式（希尔记法）:

C₁₁H₇ClN₄O

CAS号:

2281899-12-3

分子量:

246.65

MDL號碼:

MFCD32672303

分類程式碼代碼:

12352101

NACRES:

NA.22

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化驗

≥95%

形狀

powder

反應適用性

reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation

mp

156-159 °C

儲存溫度

−20°C

SMILES 字串

Clc1nc(nc(n1)c2c(cccc2)C#N)OC

應用

2-(4-Chloro-6-methoxy-1,3,5-triazin-2-yl)benzonitrile is a bifunctional C-H activation template developed in the Yu lab for the conversion of phenols to 1,3-disubstituted arenes. The template is used for a one-pot Pd-catalyzed meta-selective C-H olefination of phenols followed by a nickel-catalyzed ipso-C-O activation and arylation.

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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Sequential Functionalization of meta-C-H and ipso-C-O Bonds of Phenols.

Jiancong Xu et al.

Journal of the American Chemical Society, 141(5), 1903-1907 (2019-01-23)

The use of a template as a linchpin motif in directed remote C-H functionalization is a versatile yet relatively underexplored strategy. We have developed a template-directed approach to realizing one-pot sequential palladium-catalyzed meta-selective C-H olefination of phenols, and nickel-catalyzed ipso-C-O

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主要文件

2-(4-Chloro-6-methoxy-1,3,5-triazin-2-yl)benzonitrile