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Merck

932744

Sigma-Aldrich

Tris[2-(p-tolyl)pyridine]iridium(III)

≥99% (HPLC)

别名:

Ir(p-Me-ppy)3 , Ir(mppy)3

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About This Item

经验公式(希尔记法):
C36H30IrN3
分子量:
696.86
MDL號碼:
分類程式碼代碼:
12352302
NACRES:
NA.21

等級

sublimed grade

品質等級

化驗

≥99% (HPLC)

損耗

0.5% TGA, >330°C (weight loss)

溶解度

chloroform: soluble
dichloromethane: soluble
toluene: soluble

λmax

287 nm±5 nm in dichloromethane
373 nm±5 nm in dichloromethane

螢光

λem 514 nm±10 nm in dichloromethane

軌道能量

HOMO 5.6 eV 
LUMO 3.0 eV 

SMILES 字串

[Ir](c5c(ccc(c5)C)c6ncccc6)(c3c(ccc(c3)C)c4ncccc4)c1c(ccc(c1)C)c2ncccc2

InChI

1S/3C12H10N.Ir/c3*1-10-5-7-11(8-6-10)12-4-2-3-9-13-12;/h3*2-7,9H,1H3;

InChI 密鑰

OJLAFZLERCHWGI-UHFFFAOYSA-N

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應用

Tris[2-(p-tolyl)pyridine]iridium(III), also known as Ir(mppy)3, is a solution-processable small molecule, used as green phosphorescent dopant in highly-efficient light emitting diode (LED) displays, both perovskite and organic LEDs.
Tris[2-(p-tolyl)pyridine]iridium(III) is widely utilized as a phosphorescent emitter in OLED devices, particularly in green or yellow organic light-emitting diodes (OLEDs). It can be used in R&D studies for the development of advanced display technologies, including flat-panel displays and organic electroluminescent (OEL) displays. It is suitable in studies such as solid-state lighting including white OLEDs (WOLEDs) and organic light-emitting transistors (OLETs). It has been studied as a sensitizer in dye-sensitized solar cells (DSSCs), as a component in hybrid perovskite solar cells. It can be used in the research area of chemical sensor applications.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Highly efficient green single-emitting layer phosphorescent organic light-emitting diodes with an iridium(III) complex as a hole-type sensitizer
Wu R, et al.
Journal of Material Chemistry C, 7, 2744-2750 (2019)

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