932469

4,4′,4′′-Tris(N-(naphthalen-2-yl)-N-phenyl-amino)-triphenylamine

• 别名: TSPO1, Diphenyl(4-(triphenylsilyl)phenyl)phosphine oxide
• 经验公式（希尔记法）: C₃₆H₂₉OPSi
• CAS号: 1286708-86-8
• 分子量: 536.67
• MDL號碼: MFCD31657507
• 分類程式碼代碼: 12352116
• NACRES: NA.23

属性

• 等級: sublimed grade
• 品質等級: 100
• 描述: μh ≈ 1.1 x 10^-6 cm² V⁻¹ s⁻¹; μe ≈ 5.7 x 10^-6 cm² V⁻¹ s⁻¹
• 化驗: ≥97% (HPLC)
• 損耗: 0.5% TGA, > 300 °C (weight loss)
• mp: 236 °C
• 溶解度: chloroform: soluble; dichloromethane: soluble; toluene: soluble
• λmax: 266 nm±5 nm in dichloromethane
• 螢光: λ_em 298 nm±10 nm in dichloromethane
• 軌道能量: HOMO 6.79 eV ; LUMO 2.52 eV
• SMILES 字串: [Si](c4ccc(cc4)[P](=O)(c6ccccc6)c5ccccc5)(c3ccccc3)(c2ccccc2)c1ccccc1
• InChI: 1S/C36H29OPSi/c37-38(30-16-6-1-7-17-30,31-18-8-2-9-19-31)32-26-28-36(29-27-32)39(33-20-10-3-11-21-33,34-22-12-4-13-23-34)35-24-14-5-15-25-35/h1-29H
• InChI 密鑰: TXBFHHYSJNVGBX-UHFFFAOYSA-N

说明

應用

4,4′,4′′-Tris(N-(naphthalen-2-yl)-N-phenyl-amino)-triphenylamine (TSPO1), also known as diphenyl(4-(triphenylsilyl)phenyl)phosphine oxide, is popularly used as a solution-processable phosphorescent host in optoelectronic devices. It has a μh around 1.1 x 10^-6 cm² V⁻¹ s⁻¹ and a μe of about 5.7 x 10^-6 cm² V⁻¹ s⁻¹.

安全信息

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable