推荐产品
产品名称
对硝基苯基三甲基硅乙基碳酸酯, ≥97.0%
品質等級
化驗
≥97.0%
形狀
crystals
mp
35-40 °C
應用
peptide synthesis
官能基
carbonate
nitro
儲存溫度
2-8°C
SMILES 字串
C[Si](C)(C)CCOC(=O)Oc1ccc(cc1)[N+]([O-])=O
InChI
1S/C12H17NO5Si/c1-19(2,3)9-8-17-12(14)18-11-6-4-10(5-7-11)13(15)16/h4-7H,8-9H2,1-3H3
InChI 密鑰
ZAQWGGKIMQIVGM-UHFFFAOYSA-N
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應用
4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate can be used as:
- A protecting group for an amine in one of the key synthetic steps of kottamide E total synthesis.
- A starting material to prepare a cis-butene derivative, which is used as a polymer terminating agent in the synthesis of monotelechelic glycopolymers.
其他說明
用于引入 TEOC-氨基保护基团的试剂,TEOC-氨基保护基团可被 F- 裂解
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
其他客户在看
The Journal of Organic Chemistry, 54, 5551-5551 (1989)
Journal of the Chemical Society. Chemical Communications, 358-358 (1978)
Hoppe-Seyler's Zeitschrift fur physiologische Chemie, 362(9), 1289-1292 (1981-09-01)
2-(Trimethylsilyl)ethyl-4-nitrophenyl carbonate has been prepared as a new reagent for the introduction of the 2-(trimethylsilyl)ethyloxycarbonyl group into amino acids or amino acid derivatives. The resulting N alpha-protected amino acids were found to represent suitable intermediates for the synthesis of peptides.
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