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911984

Sigma-Aldrich

(2,2′-Bipyridine)diiodonickel(II)

别名:

(bpy)NiI2

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About This Item

经验公式（希尔记法）:
C10H8I2N2Ni
CAS号:
59448-25-8
分子量:
468.69
MDL號碼:
MFCD32672292
分類程式碼代碼:
12352101
NACRES:
NA.22

形狀

powder or crystals

反應適用性

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

SMILES 字串

[Ni]1([NH]2=C(C3=[NH]1C=CC=C3)C=CC=C2)(I)I

InChI 密鑰

HXZGEUKJJFSILG-UHFFFAOYSA-L

相关类别

應用

(2,2′-Bipyridine)diiodonickel(II) is a catalyst for the cross-electrophile coupling of vinyl halides and alkyl halides.

其他說明

Synthesis of Tetrasubstituted Alkenes by Tandem Metallacycle Formation/Cross-Electrophile Coupling

訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Muta. 2 - Repr. 2 - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Kirk W Shimkin et al.
Journal of the American Chemical Society, 140(23), 7074-7078 (2018-05-26)
Nickel-catalyzed cross-electrophile couplings have recently emerged as highly effective and practical methods for the formation of C-C bonds. By merging this process with well-established π-π coupling chemistry, a new method for the synthesis of tetrasubstituted alkenes has been developed. The

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