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805238

Sigma-Aldrich

FK 102 Co(II) PF6 盐

别名:

Greatcell Solar®, tris(2-(1H-pyrazol-1-yl)pyridine)cobalt(II) di[hexafluorophosphate]

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About This Item

经验公式（希尔记法）:
C24H21CoF12N9P2
CAS号:
1392221-69-0
分子量:
784.35
MDL號碼:
MFCD29037024
分類程式碼代碼:
12352103
PubChem物質ID:
329768922
NACRES:
NA.23

化驗

98%

品質等級

100

形狀

powder

mp

362 °C

SMILES 字串

F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.N1(C2=NC=CC=C2)N=CC=C1.C3(N4C=CC=N4)=CC=CC=N3.C5(N6C=CC=N6)=CC=CC=N5.[Co+2]

InChI

1S/3C8H7N3.Co.2F6P/c3*1-2-5-9-8(4-1)11-7-3-6-10-11;;2*1-7(2,3,4,5)6/h3*1-7H;;;/q;;;+2;2*-1

InChI 密鑰

MLELXRWOHQBFBO-UHFFFAOYSA-N

相关类别

應用

Use this cobalt complexes to increase photovoltages of liquid electrolyte cells substantially or to achieve ultrahigh performance with solid state photovoltaic devices.
FK102 cobalt complexes offer guaranteed performance, high reproducibility, consistent results, and are of highest purity. In comparison to triiodide-based redox electrolytes, cobalt complexes in general increase photovoltages and particularly at lower light levels (e.g. for indoor applications), significantly increase device power output.
Recommended use:
In liquid-based electrolytes: typically 0.15-0.2M of Co(II) and ca. 0.05M Co(II)
In solid-state photovoltaic cells: up to 10 weight % added to the hole transport material system.

法律資訊

Product of Greatcell Solar Materials Pty Ltd.
Greatcell Solar is a registered trademark of Greatcell SolarMaterials Pty Ltd.
Dyesol is a registered trademark of Greatcell Solar
Greatcell Solar is a registered trademark of Greatcell Solar

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKBW1704V

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Sandra M Feldt et al.
Physical chemistry chemical physics : PCCP, 15(19), 7087-7097 (2013-04-05)
Regeneration and recombination kinetics was investigated for dye-sensitized solar cells (DSCs) using a series of different cobalt polypyridine redox couples, with redox potentials ranging between 0.34 and 1.20 V vs. NHE. Marcus theory was applied to explain the rate of
Teck Ming Koh et al.
ChemSusChem, 7(7), 1909-1914 (2014-05-23)
In this work, we report a new cobalt(III) complex, tris[2-(1H-pyrazol-1-yl)pyrimidine]cobalt(III) tris[bis(trifluoromethylsulfonyl)imide] (MY11), with deep redox potential (1.27 V vs NHE) as dopant for 2,2',7,7'-tetrakis-(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD). This dopant possesses, to the best of our knowledge, the deepest redox potential among all
Edoardo Mosconi et al.
Journal of the American Chemical Society, 134(47), 19438-19453 (2012-11-02)
We report a combined experimental and computational investigation to understand the nature of the interactions between cobalt redox mediators and TiO(2) surfaces sensitized by ruthenium and organic dyes, and their impact on the performance of the corresponding dye-sensitized solar cells
Julian Burschka et al.
Nature, 499(7458), 316-319 (2013-07-12)
Following pioneering work, solution-processable organic-inorganic hybrid perovskites-such as CH3NH3PbX3 (X = Cl, Br, I)-have attracted attention as light-harvesting materials for mesoscopic solar cells. So far, the perovskite pigment has been deposited in a single step onto mesoporous metal oxide films

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