794279

Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)

• 别名: Buchwald Nickel Cross-Coupling Catalyst Precursor, [Bis(triphenylphosphine)](o-tolyl)chloronickel
• 经验公式（希尔记法）: C₄₃H₃₇ClNiP₂
• CAS号: 27057-09-6
• 分子量: 709.85
• 分類程式碼代碼: 12161600
• PubChem物質ID: 329768436
• NACRES: NA.22

属性

• 形狀: solid
• 品質等級: 100
• 反應適用性: core: nickel; reagent type: catalyst
• mp: 195-200 °C
• 儲存溫度: 2-8°C
• SMILES 字串: Cl[Ni]C1=CC=CC=C1C.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7
• InChI: 1S/2C18H15P.C7H7.ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;/h2*1-15H;2-5H,1H3;1H;/q;;;;+1/p-1
• InChI 密鑰: QVGJKVLYWZGANE-UHFFFAOYSA-M

说明

應用

Product is a precursor to the synthesis of an air-stable Ni-precatalyst developed by Buchwald and coworkers.

其他說明

Development of an Air-Stable Nickel Precatalyst for the Amination of Aryl Chlorides, Sulfamates, Mesylates, and Triflates

安全信息

• 象形圖: GHS08,GHS07
• 訊號詞: Danger
• 危險聲明: H317,H350
• 防範說明: P201 - P280 - P302 + P352 - P308 + P313
• 危險分類: Carc. 1B - Skin Sens. 1
• 儲存類別代碼: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable