739103

Ru-MACHO^®

• 别名: {双[2-(二苯基膦基)乙基]胺}羰基氯化氢化钌(II), 羰基氯化氢化{双[2-(二苯基膦甲基)乙基]氨基}乙基]氨基}钌(II)
• 经验公式（希尔记法）: C₂₉H₃₀ClNOP₂Ru
• CAS号: 1295649-40-9
• 分子量: 607.03
• 分類程式碼代碼: 12161600
• PubChem物質ID: 329765328
• NACRES: NA.22

属性

• 形狀: solid
• 反應適用性: core: ruthenium; reagent type: catalyst
• mp: 260-290 °C
• SMILES 字串: Cl[Ru].[C-]#[O+].C(CP(c1ccccc1)c2ccccc2)NCCP(c3ccccc3)c4ccccc4
• InChI: 1S/C28H29NP2.CO.ClH.Ru/c1-5-13-25(14-6-1)30(26-15-7-2-8-16-26)23-21-29-22-24-31(27-17-9-3-10-18-27)28-19-11-4-12-20-28;1-2;;/h1-20,29H,21-24H2;;1H;/q;;;+1/p-1
• InChI 密鑰: GQFWSAKCCNATEV-UHFFFAOYSA-M

说明

應用

<ul>
<li><strong>Dehydrogenative Intramolecular Macrolactonization:</strong> Ru-MACHO catalyst is applied in dehydrogenative intramolecular macrolactonization of dihydroxy compounds, demonstrating its efficiency in organic synthesis with potential implications for pharmaceutical synthesis (Jamdade et al., 2022).</li>
<li><strong>Acceptorless Dehydrogenation of Methanol:</strong> Employing Ru-MACHO catalyst in the acceptorless dehydrogenation of methanol to produce carbon monoxide and hydrogen, this process highlights Ru-MACHO′s capability in catalytic transformations and green chemistry applications (Kaithal et al., 2021).</li>
<li><strong>Precapture and Hydrogenation of CO₂:</strong> A study on the heterogenized Ru-MACHO catalytic systems for pre-capture and hydrogenation of CO₂ into methanol, underscoring the catalyst′s potential in sustainable chemical processes (Szego et al., 2023).</li>
<li><strong>Pressure-dependent Hydrogenative Depolymerization:</strong> The Ru-MACHO catalyst is used for highly selective pressure-dependent hydrogenative depolymerization of polybutylene succinate, demonstrating the catalyst′s versatility in polymer processing and chemical recycling (Johnson et al., 2024).</li>
</ul>

法律資訊

与Takasago合作出售，仅用于研究目的。Ru-MACHO是Takasago Intl. Corp.的注册商标。PCT/JP2010-004301。

Ru-MACHO is a registered trademark of Takasago Intl. Corp.

安全信息

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable