709492

(1S,4S,8S)-5-苄基-8-甲氧基-1,8-二甲基-2-(2′-甲基丙基)-双环[2.2.2]辛-2,5-二烯

97%

• 别名: (1S,4S,8S) Carreira DOLEFIN 配体, (1S,4S,8S)-5-苄基-2-异丁基-8-甲氧基-1,8-二甲基-2-双环[2.2.2]辛-2,5-二烯
• 经验公式（希尔记法）: C₂₂H₃₀O
• CAS号: 862499-50-1
• 分子量: 310.47
• MDL號碼: MFCD09265063
• 分類程式碼代碼: 12352112
• PubChem物質ID: 329762875
• NACRES: NA.06

属性

• 品質等級: 100
• 化驗: 97%
• 形狀: liquid
• 光學活性: [α]/D −84±5°, c = 0.5 in chloroform
• 反應適用性: reaction type: click chemistry
• 折射率: n20/D 1.522
• 官能基: ether; phenyl
• SMILES 字串: CO[C@@]1(C)C[C@@]2(C)C=C(Cc3ccccc3)[C@@H]1C=C2CC(C)C
• InChI: 1S/C22H30O/c1-16(2)11-19-13-20-18(12-17-9-7-6-8-10-17)14-21(19,3)15-22(20,4)23-5/h6-10,13-14,16,20H,11-12,15H2,1-5H3/t20-,21+,22-/m0/s1
• InChI 密鑰: ACWLDJOHMGJACE-BDTNDASRSA-N

说明

一般說明

(1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene, an enantiopure diene ligand developed by Carreira, is most commonly used in asymmetric catalysis. It is generally prepared from commercially available (R)-carvone.

應用

Carreira DOLEFIN Ligands

(1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene is mainly useful for the stereoselective synthesis of diarylmethine stereogenic centers.

安全信息

• 儲存類別代碼: 10 - Combustible liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable