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形狀
liquid
反應適用性
reagent type: reductant
環保替代產品特色
Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
濃度
10 % (w/w)
2.3 M in 2-methyltetrahydrofuran
密度
0.883 g/mL at 25 °C
環保替代類別
, Aligned
儲存溫度
2-30°C
SMILES 字串
[Li+].[AlH4-]
InChI
1S/Al.Li.4H/q-1;+1;;;;
InChI 密鑰
OCZDCIYGECBNKL-UHFFFAOYSA-N
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一般說明
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 2.3 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Click here for more information.
應用
反应物或试剂用于:
LAH 是许多不同还原反应的强还原剂,例如酮类与醇类的还原反应
- 由油酸制备热塑性聚酯聚酰胺
- 锂聚合物电池
- 宝石-二氟亚甲基衍生物的加氢脱氟
- 不对称羟醛反应
- 具有吸氢/解吸特性的 Li-Al-N-H 复合材料的合成
LAH 是许多不同还原反应的强还原剂,例如酮类与醇类的还原反应
Powerful reducing agent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - Water-react 1
安全危害
儲存類別代碼
4.3 - Hazardous materials which set free flammable gases upon contact with water
水污染物質分類(WGK)
WGK 2
閃點(°F)
10.4 °F - closed cup - Solvent
閃點(°C)
-12 °C - closed cup - Solvent
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
The Journal of antibiotics, 57(1), 52-58 (2004-03-23)
Planar structures of tripropeptins (TPPs) were elucidated by spectroscopic studies including various NMR measurements. Stereochemistry of constituent amino acids of tripropeptin C (TPPC) (3) was identified by marfey's method except hydroxyproline which was determined by studies of NMR and CD
Journal of neuropathology and experimental neurology, 68(8), 870-879 (2009-07-17)
Previous studies indicate that RNA may be required for proteinase-resistant prion protein (PrP) amplification and for infectious prion formation in vitro, suggesting that RNA molecules may function as cellular cofactors for abnormal PrP (PrPSc) formation and become part of the
Chemical & pharmaceutical bulletin, 50(9), 1273-1275 (2002-09-19)
Two new migrated hopane triterpenoids, viz. 4alpha-hydroxyfilican-3-one and fern-9(11)-en-12beta-ol, and olean-18-en-3-one and olean-12-en-3-one as the first example of oleanane compounds from Adiantum ferns were isolated along with many other known triterpenoids from Adiantum capillus-veneris of China and Egypt. Their structures
Inorganic chemistry, 44(15), 5286-5292 (2005-07-19)
The nature of the solute species present in ethereal solutions of LiAlH(4) is of crucial importance for understanding the mechanisms for the reduction of ketones and other functional groups by LiAlH(4). We have employed a combination of theoretical and experimental
Organic letters, 4(14), 2445-2448 (2002-07-06)
[reaction: see text] The stereospecific alpha-lithiation of optically active styrene oxides and the trapping reaction of the corresponding highly reactive intermediates with electrophiles to produce optically active styrene oxide derivatives are described. This methodology has been applied to the synthesis
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