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Merck

703206

Sigma-Aldrich

-双(异硫氰酸盐)双(2,2′-联吡啶-4,4′-二羧酸钌 (II)

别名:

Greatcell Solar®, N-3 染料

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About This Item

经验公式(希尔记法):
C26H16N6O8RuS2
分子量:
705.64
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.23

化驗

95% (NMR)

形狀

powder

mp

>300 °C

λmax

534, 395, 312 nm (lit.)

SMILES 字串

S=C=N[Ru]N=C=S.OC(=O)c1ccnc(c1)-c2cc(ccn2)C(O)=O.OC(=O)c3ccnc(c3)-c4cc(ccn4)C(O)=O

InChI

1S/2C12H8N2O4.2CNS.Ru/c2*15-11(16)7-1-3-13-9(5-7)10-6-8(12(17)18)2-4-14-10;2*2-1-3;/h2*1-6H,(H,15,16)(H,17,18);;;/q;;2*-1;+2

InChI 密鑰

VMISXESAJBVFNH-UHFFFAOYSA-N

一般說明

顺式双(异硫氰酸基)双(2,2′-联吡啶基-4,4′-二羧甲基)钌(II) (N3 染料) 是一种钌聚吡啶基络合物,可用作敏化剂。它是一种高度稳定的聚合物,其光电流随N3染料的浓度上升而下降。

應用

N3染料可以涂覆在电极上,以增强染料敏化太阳能电池(DSSC)的灵敏度,该电池可进一步增强功率转换效率(PCE)。

法律資訊

Greatcell Solar Materials Pty Ltd.公司产品
Greatcell Solar 是 Greatcell Solar Materials Pty Ltd公司的注册商标。
Dyesol is a registered trademark of Greatcell Solar

象形圖

Exclamation mark

訊號詞

Warning

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Transport-limited recombination of photocarriers in dye-sensitized nanocrystalline TiO2 solar cells
Kopidakis N, et al.
The Journal of Physical Chemistry B, 107(41), 11307-11315 (2003)
Stark effects after excited-state interfacial electron transfer at sensitized TiO2 nanocrystallites
Ardo S, et al.
Journal of the American Chemical Society, 132(19), 6696-6709 (2010)
Influence of electrolyte in transport and recombination in dye-sensitized solar cells studied by impedance spectroscopy
Fabregat-Santiago F, et al.
Solar Energy Materials and Solar Cells, 87(1-4), 117-131 (2005)
Determination of the electron lifetime in nanocrystalline dye solar cells by open-circuit voltage decay measurements
Zaban A, et al.
ChemPhysChem, 4(8), 859-864 (2003)
Ruthenium (II) Charge-Transfer Sensitizers Containing 4, 4 `-Dicarboxy-2, 2 `-bipyridine. Synthesis, Properties, and Bonding Mode of Coordinated Thio-and Selenocyanates
Kohle O, et al.
Inorganic Chemistry, 35(16), 4779-4787 (1996)

商品

Dye solar cells (DSCs) are third generation solar cells with the promise of high efficiency combined with low production costs. While present day DSCs provide light-to-electricity conversion of up to 11%, significant further improvement is envisaged through optimized materials and novel cell and module architectures.

Dye-sensitized solar cells directly convert sunlight to electricity

Over the last decade, dye-sensitized solar cells (DSSCs) have attracted much attention because these unconventional solar cells exhibit high performance and have the potential for low-cost production.

Dye-sensitized solar cells (DSCs) are 3rd generation solar cells combining the promise of high efficiency with low production costs.

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