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700762

(S)-SIPHOS-PE

Name: (<I>S</I>)-SIPHOS-PE
Brand: ALDRICH

97%

别名:

(11aS)-(-)-10,11,12,13-四氢茚并[7,1-de:1′, 7′-fg][1,3,2]二氧磷-5-双[(R)-1-苯乙基]胺, N-二[(R)-1-苯乙基]-[(S)-1,1′-螺二氢茚-7,7′-二基]亚磷酰胺

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About This Item

经验公式（希尔记法）:

C₃₃H₃₂NO₂P

CAS号:

500997-70-6

分子量:

505.59

MDL號碼:

MFCD08459342

分類程式碼代碼:

12352005

PubChem物質ID:

329762229

NACRES:

NA.22

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品質等級

100

化驗

97%

形狀

powder

光學活性

[α]22/D −65.0°, c = 1 in chloroform

mp

120-125 °C

官能基

amine
phenyl

儲存溫度

−20°C

SMILES 字串

C[C@@H](N([C@H](C)c1ccccc1)P2Oc3cccc4CCC5(CCc6cccc(O2)c56)c34)c7ccccc7

InChI

1S/C33H32NO2P/c1-23(25-11-5-3-6-12-25)34(24(2)26-13-7-4-8-14-26)37-35-29-17-9-15-27-19-21-33(31(27)29)22-20-28-16-10-18-30(36-37)32(28)33/h3-18,23-24H,19-22H2,1-2H3/t23-,24-,33?/m1/s1

InChI 密鑰

ZXLQLIDJAURBDD-HRPAVAKOSA-N

應用

(S)-SIPHOS-PE is a chiral spiro phosphoramidate ligand that can be used to synthesize:

Spiroindolenines by Pd-catalyzed intramolecular dearomative arylation of haloaryl-3-substituted indoles.
Enantioselective conjugate addition compound by Cu-catalyzed 1,4-addition of diethylzinc (Et₂Zn) to cyclic enones.
Octaketide natural products via rhodium-phosphoramidite catalyzed alkene hydroacylation.