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形狀
liquid
反應適用性
core: copper
reagent type: catalyst
濃度
in anhydrous tetrahydrofuran
密度
0.999 g/mL at 25 °C
SMILES 字串
[Li]Cl.[Li]Cl.[Cu]C#N
InChI
1S/CN.2ClH.Cu.2Li/c1-2;;;;;/h;2*1H;;;/q;;;;2*+1/p-2
InChI 密鑰
QGXKBLXNBYNHBV-UHFFFAOYSA-L
應用
氰化亚铜(I)二(氯化锂)配合物可用于,通过有机锌 和格氏(Grignard)试剂的转移金属化合成有机铜(I)试剂。 也是制备有机铜(I)试剂的有用前体。
訊號詞
Danger
危險分類
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Central nervous system, Respiratory system
安全危害
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 2
閃點(°F)
1.4 °F - closed cup - Solvent
閃點(°C)
-17 °C - closed cup - Solvent
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
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Angewandte Chemie (International Edition in English), 36, 186-186 (1997)
The Journal of organic chemistry, 67(25), 8726-8743 (2002-12-07)
Biocatalytic approaches have yielded efficient total syntheses of the major Amaryllidaceae alkaloids, all based on the key enzymatic dioxygenation of suitable aromatic precursors. This paper discusses the logic of general synthetic design for lycoricidine, narciclasine, pancratistatin, and 7-deoxypancratistatin. Experimental details
TMPZnCl?LiCl: A new active selective base for the directed zincation of sensitive aromatics and heteroaromatics.
Organic Letters, 11(8), 1837-1840 (2009)
The Journal of organic chemistry, 68(11), 4371-4381 (2003-05-24)
2,5,6-Trisubstituted piperidines are readily prepared by a combination of an aza-Achmatowicz oxidation of a furyl-substituted benzenesulfonamide followed by a conjugate addition to the resulting 2H-pyridone and subsequent addition of various nucleophiles to a transient N-sulfonyliminium ion. The stereochemistry of the
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