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Merck

686859

Sigma-Aldrich

1,3,5-三(4-羧基苯基)苯

greener alternative

≥98%, ≤20 wt. % solvent

别名:

4,4′,4′′-苯-1,3,5-三基-三(苯甲酸), H3BTB

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About This Item

经验公式(希尔记法):
C27H18O6
CAS号:
分子量:
438.43
MDL號碼:
分類程式碼代碼:
26111700
PubChem物質ID:
NACRES:
NA.23

化驗

≥98%

形狀

solid

環保替代產品特色

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

雜質

≤20 wt. % solvent

mp

322-327 °C

環保替代類別

SMILES 字串

OC(=O)c1ccc(cc1)-c2cc(cc(c2)-c3ccc(cc3)C(O)=O)-c4ccc(cc4)C(O)=O

InChI

1S/C27H18O6/c28-25(29)19-7-1-16(2-8-19)22-13-23(17-3-9-20(10-4-17)26(30)31)15-24(14-22)18-5-11-21(12-6-18)27(32)33/h1-15H,(H,28,29)(H,30,31)(H,32,33)

InChI 密鑰

SATWKVZGMWCXOJ-UHFFFAOYSA-N

一般說明

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應用

1,3,5-三(4-羧基苯基)苯 (BTB) 可作为金属有机框架 (MOF) 的结构单元。MOF 为三维微孔材料,具有气体吸附和分离技术领域的应用前景。BTB 新近用作构造具有极大表面积的 MOF 的键接,如 MOF-177(约 5000m2/g),它是一种氢吸附材料,77K 下储氢容量高达 7.5%。
1,3,5-三(4-羧基苯基)苯(H3BTB)是一种星形二维分子,可通过各种底物形成自组装单层膜(SAM) 。它可用作三配位(tritopic)桥联配体,促进多金属氧酸盐类金属有机框架(MOF)的官能化,以用于气体储存、气体分离和催化。

訊號詞

Danger

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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其他客户在看

Chong Liu et al.
Faraday discussions, 201, 163-174 (2017-06-18)
Gradient MOFs contain directional gradients of either structure or functionality. We have successfully prepared two ternary gradient MOFs based on bMOF-100 analogues, namely bMOF-100/102/106 and bMOF-110/100/102, via cascade ligand exchange reactions. The cubic unit cell parameter discrepancy within an individual
Meng-Yao Chao et al.
Dalton transactions (Cambridge, England : 2003), 47(38), 13722-13729 (2018-09-15)
The two-dimensional (2D) metal-organic framework (MOF) [Cd2.25Co0.75(BTB)2(DEF)4]·2(DEF)0.5 (1a, BTB = benzene-1,3,5-tribenzolate; DEF = N,N'-diethylformamide) featuring linear trimetallic cluster secondary building units (SBUs) and replaceable DEF solvates reacts smoothly with dipyridyl ligands DPS, DPDS, and BIPY (DPS = 4,4'-dipyridyl sulfide; DPDS
Ram R R Prasad et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 24(57), 15309-15318 (2018-07-07)
Post-synthetic modification of the hafnium metal-organic framework MOF-808(Hf) to include triarylphosphine ligands is reported. Sulfonated phenylphosphines are incorporated without oxidation to give a "MOF ligand" that can complex late transition metals such as Ir and Rh to give a bifunctional
Alejandro Cabrera-García et al.
Journal of colloid and interface science, 541, 163-174 (2019-01-28)
MIL-100(Fe) and MIL-101(Fe) metal-organic frameworks (MOFs) are excellent vehicles for drug delivery systems (DDSs) due to their high biocompatibility and stability in physiological fluids, as well as their pore diameter in the mesoporous range. Although they are appropriate for the
Seung Bin Baek et al.
Proceedings of the National Academy of Sciences of the United States of America, 112(46), 14156-14161 (2015-11-19)
Crystallographic observation of adsorbed gas molecules is a highly difficult task due to their rapid motion. Here, we report the in situ single-crystal and synchrotron powder X-ray observations of reversible CO2 sorption processes in an apparently nonporous organic crystal under

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