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680990

Sigma-Aldrich

1,1′-双[(2R,5R)-2,5-二乙基膦烷基]二茂铁

别名:

R,R-Et-Ferrocelane™

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About This Item

经验公式（希尔记法）:
C26H40FeP2
CAS号:
147762-89-8
分子量:
470.39
MDL號碼:
MFCD09265149
分類程式碼代碼:
12352005
PubChem物質ID:
24885607
NACRES:
NA.22

形狀

solid

品質等級

100

光學活性

[α]20/D +380°, c = 1 in chloroform

mp

85-91 °C

官能基

phosphine

SMILES 字串

C[Fe]C.CC[C@@H]1CC[C@@H](CC)P1[C@@H]2CCCC2.CC[C@@H]3CC[C@@H](CC)P3[C@H]4CCCC4

InChI

1S/2C13H25P.2CH3.Fe/c2*1-3-11-9-10-12(4-2)14(11)13-7-5-6-8-13;;;/h2*11-13H,3-10H2,1-2H3;2*1H3;/t2*11-,12-;;;/m11.../s1

InChI 密鑰

CPUKIDAUDCWIRT-QULUYMGFSA-N

相关类别

應用

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
1,1′-Bis[(2R,5R)-2,5-diethylphospholano]ferrocene can be used:
  • As a catalyst in the asymmetric hydrogenation reactions of olefins and ketones.
  • As a component of a rhodium based precatalyst, applicable in the 2-methylenesuccinamic acid hydrogenation reaction.

法律資訊

与 Kanata Chemical Technologies Inc. 联合销售，仅供研究使用。这些化合物由 E.I. du Pont de Nemours and Company 授权制造和销售，此许可不包括利用这些化合物制备在制药领域销售的产品的权利。
Ferrocelane is a trademark of Kanata Chemical Technologies, Inc.

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
11106TE

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Highly efficient asymmetric hydrogenation of 2-Methylenesuccinamic acid using a Rh-DuPHOS catalyst
Cobley CJ, et al.
Organic Process Research & Development, 7(3), 407-411 (2003)

商品

DuPhos and BPE Ligands

Asymmetric hydrogenation reactions represent the ideal process for the commercial manufacture of single-enantiomer compounds, because of the ease by which these robust procedures can be scaled up and because of the low levels of byproducts generated in these asymmetric hydrogenations.

DuPhos and BPE Ligands

Asymmetric hydrogenation reactions represent the ideal process for the commercial manufacture of single-enantiomer compounds, because of the ease by which these robust procedures can be scaled up and because of the low levels of byproducts generated in these asymmetric hydrogenations.

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