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674583

Sigma-Aldrich

高氯酸银

anhydrous, 97%

别名:

Perchloric acid silver(1+) salt, Silver(1+) perchlorate

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About This Item

线性分子式:
AgClO4
CAS号:
7783-93-9
分子量:
207.32
EC號碼:
232-035-4
MDL號碼:
MFCD00003400
分類程式碼代碼:
12352302
PubChem物質ID:
24885223
NACRES:
NA.23

等級

anhydrous

品質等級

100

化驗

97%

形狀

solid

反應適用性

reagent type: catalyst
core: silver

雜質

≤0.1% Insoluble matter

mp

486 °C (lit.)

溶解度

benzene: slightly soluble(lit.)
pyridine: slightly soluble(lit.)

密度

2.8 g/mL at 25 °C (lit.)

SMILES 字串

[Ag+].[O-]Cl(=O)(=O)=O

InChI

1S/Ag.ClHO4/c;2-1(3,4)5/h;(H,2,3,4,5)/q+1;/p-1

InChI 密鑰

YDHABVNRCBNRNZ-UHFFFAOYSA-M

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應用

  • Anion exchange dynamics in the capture of perchlorate by a cationic Ag-based MOF：研究银基金属有机骨架捕获高氯酸盐的阴离子交换动力学和结构转换(Colinas et al., 2017)。

象形圖

Flame over circleCorrosion
GHS03,GHS05

訊號詞

Danger

危險聲明

H272,H314

危險分類

Ox. Sol. 2 - Skin Corr. 1B

儲存類別代碼

5.1A - Strongly oxidizing hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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分析证书(COA)

Lot/Batch Number
MKCQ4873
MKCN3382
MKCL7961
MKCJ3240
MKCJ3239

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Glycosylation via Cp2ZrCl2/AgClO4-mediated activation of anomeric sulfoxides.
P Wipf et al.
The Journal of organic chemistry, 66(23), 7910-7914 (2001-11-10)
Ken Sakai et al.
Acta crystallographica. Section B, Structural science, 60(Pt 3), 255-262 (2004-05-19)
The third crystal structure containing the hydroxo-bridged cis-diammineplatinum(II) dimer has been determined for a perchlorate salt of the complex, [Pt(2)(NH(3))(4)(micro-OH)(2)](ClO(4))(2). However, the dinuclear cations in the nitrate and the carbonate salts, [Pt(2)(NH(3))(4)(micro-OH)(2)](NO(3))(2) [Faggiani, Lippert, Lock & Rosenberg (1977). J. Am.
Masafumi Harada et al.
Journal of colloid and interface science, 339(2), 373-381 (2009-09-08)
Metal particles of silver (Ag) were synthesized by the photoreduction of silver perchlorate (AgClO(4)) in water-in-ionic liquid (ILs) microemulsions consisting of Tween 20, water and ionic liquids. The ILs were tetrafluoroborate anions associated with the cations 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF(4)]) and
E Petráková et al.
Carbohydrate research, 233, 101-112 (1992-09-02)
Specifically deoxygenated methyl alpha-isomaltotriosides were synthesized by the silver perchlorate-mediated condensation of a protected alpha-isomaltosyl chloride with suitably blocked derivatives of methyl alpha-D-glucopyranoside deoxygenated respectively at positions 2, 3, and 4, followed by deprotection.
C Rentel et al.
Analytical chemistry, 70(20), 4394-4400 (1998-10-31)
In LC/MS, nonpolar substances in the majority of cases cannot be ionized by standard electrospray ionization (ESI) because they obviously lack a site for protonation or deprotonation. The ionization of carotenoids and tocopherols can be greatly enhanced by the addition
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