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661384

Sigma-Aldrich

2-碘酰基苯甲酸

contains stabilizer, 45 wt. % (IBX)

别名:

2-碘酰苯甲酸, SIBX

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About This Item

经验公式（希尔记法）:
C7H5IO4
CAS号:
61717-82-6
分子量:
280.02
MDL號碼:
MFCD02912492
分類程式碼代碼:
12352005
PubChem物質ID:
24884529
NACRES:
NA.22

形狀

solid

品質等級

100

包含

stabilizer

反應適用性

reagent type: oxidant

濃度

45 wt. % (IBX)

SMILES 字串

OI1(=O)OC(=O)c2ccccc12

InChI

1S/C7H5IO4/c9-7-5-3-1-2-4-6(5)8(10,11)12-7/h1-4H,(H,10,11)

InChI 密鑰

CQMJEZQEVXQEJB-UHFFFAOYSA-N

相关类别

應用

稳定的2-碘氧基苯甲酸
是 IBX 的稳定形态 (SIBX)，不具有 IBX 的任何易爆性，同时保持了出色的反应性和选择性。
用于在 DMSO 存在的条件下将芴甲氧羰基保护的氨基醇氧化为相应的氨基醛的试剂。

其他說明

本品在苯甲酸和间苯二甲酸中稳定。

訊號詞

Danger

危險聲明

H314,H335,H372

危險分類

Eye Dam. 1 - Skin Corr. 1 - STOT RE 1 Inhalation - STOT SE 3

標靶器官

Lungs, Respiratory system

安全危害

EUH044

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

从最新的版本中选择一种：

分析证书(COA)

Lot/Batch Number
MKCP2346
MKCJ3996
MKCK0182
MKCB7589
MKBV2178V

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Aurélie Ozanne et al.
Organic letters, 5(16), 2903-2906 (2003-08-02)
[reaction: see text] SIBX is a nonexplosive formulation of IBX that can be used as a suspension in a variety of standard organic solvents such as refluxing EtOAc and THF to oxidize safely alcohols into aldehydes and ketones. The use
Roberta Bernini et al.
Journal of agricultural and food chemistry, 65(31), 6506-6512 (2017-03-14)
A hydroxytyrosol (HTyr)-enriched fraction containing HTyr 6% w/w, derived from Olea europaea L. byproducts and obtained using an environmentally and economically sustainable technology, was lipophilized under green chemistry conditions. The effects of three fractions containing hydroxytyrosyl butanoate, octanoate, and oleate
Synthetic Communications, 37, 3493-3493 (2007)
Celine L Hartman et al.
Journal of lipid research, 59(1), 113-122 (2017-11-24)
Endothelial dysfunction is a hallmark of multiple inflammatory diseases. Leukocyte interactions with the endothelium have significant effects on vascular wall biology and pathophysiology. Myeloperoxidase (MPO)-derived oxidant products released from leukocytes are potential mediators of inflammation and endothelial dysfunction. 2-Chlorofatty acids
Jane McHowat et al.
Frontiers in physiology, 11, 460-460 (2020-05-28)
Endothelial activation and dysfunction are hallmarks of inflammation. Neutrophil-vascular endothelium interactions have significant effects on vascular wall physiology and pathology. Myeloperoxidase (MPO)-derived products released from activated neutrophils can mediate the inflammatory response and contribute to endothelial dysfunction. 2-Chlorofatty aldehyde (2-ClFALD)

商品

Stabilized 2-Iodoxybenzoic Acid (SIBX)

IBX is not often used due to the fact that it is an impact-sensitive explosive material, which prevents its shipping and transport, as well as its application in industry.

Stabilized 2-Iodoxybenzoic Acid (SIBX)

IBX is not often used due to the fact that it is an impact-sensitive explosive material, which prevents its shipping and transport, as well as its application in industry.

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