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Merck

597910

Sigma-Aldrich

(4-氯苯基)三乙氧基硅烷

97%

别名:

氯代苯基三乙氧基硅烷

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About This Item

线性分子式:
ClC6H4Si(OC2H5)3
CAS号:
分子量:
274.82
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

97%

折射率

n20/D 1.474 (lit.)

bp

82-84 °C/0.07 mmHg (lit.)

密度

1.069 g/mL at 25 °C (lit.)

官能基

chloro

SMILES 字串

CCO[Si](OCC)(OCC)c1ccc(Cl)cc1

InChI

1S/C12H19ClO3Si/c1-4-14-17(15-5-2,16-6-3)12-9-7-11(13)8-10-12/h7-10H,4-6H2,1-3H3

InChI 密鑰

AFILDYMJSTXBAR-UHFFFAOYSA-N

應用

(4-Chlorophenyl)triethoxysilane can be used:
  • To facilitate the connection between dipolar mixed monolayers and zinc oxide in photovoltaic devices.
  • As a substrate in the Ni-catalyzed decarboxylative coupling with alkynyl carboxylic acids to yield substituted diarylalkynes.
  • As a substrate in the Hiyama cross-coupling reactions with 3-iodoazetidines to yield substituted 3-arylazetidines.
  • As an intermediate in the synthesis of tripod-shaped oligo(p-phenylene)s, which are used in the surface immobilization of gold and CdS quantum dots for sensor applications.

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

>230.0 °F - closed cup

閃點(°C)

> 110 °C - closed cup

個人防護裝備

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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分析证书(COA)

Lot/Batch Number

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访问文档库

Denmark, S. E.; Ober, M. H.
Aldrichimica Acta, 36, 75-75 (2003)

商品

A viable alternative to the popular Stille and Suzuki coupling reactions mainly due to the formation of nontoxic byproducts and stability to many reaction conditions.

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