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541486

Sigma-Aldrich

2,6-二甲基-4-庚醇

80%

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About This Item

线性分子式:
CH3CH(CH3)CH2CH(OH)CH2CH(CH3)CH3
CAS号:
108-82-7
分子量:
144.25
EC號碼:
203-619-6
MDL號碼:
MFCD00008944
分類程式碼代碼:
12352100
PubChem物質ID:
24878539
NACRES:
NA.22

品質等級

100

化驗

80%

折射率

n20/D 1.423 (lit.)

bp

178 °C (lit.)

密度

0.809 g/mL at 25 °C (lit.)

SMILES 字串

CC(C)CC(O)CC(C)C

InChI

1S/C9H20O/c1-7(2)5-9(10)6-8(3)4/h7-10H,5-6H2,1-4H3

InChI 密鑰

HXQPUEQDBSPXTE-UHFFFAOYSA-N

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應用

2,6-Dimethyl-4-heptanol may be used in the preparation of the protected β-hydroxybutyrates. It may also be used as a hydrogen donor during the dynamic kinetic resolution (DKR) of various diols, monoprotected diols and the protected hydroxy aldehydes.

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 2

閃點（°F）

150.8 °F - closed cup

閃點（°C）

66 °C - closed cup

個人防護裝備

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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2,4-二甲基-3-戊醇 99%

Sigma-Aldrich

150045

2,4-二甲基-3-戊醇

2-乙基-1-己醇 ≥99.6%

Sigma-Aldrich

538051

2-乙基-1-己醇

Dynamic kinetic resolution of secondary alcohols by enzyme?metal combinations in ionic liquid.
Kim MJ, et al.
Green Chemistry, 6(9), 471-474 (2004)
Lipase/ruthenium-catalyzed dynamic kinetic resolution of hydroxy acids, diols, and hydroxy aldehydes protected with a bulky group.
M J Kim et al.
The Journal of organic chemistry, 66(13), 4736-4738 (2001-06-26)
Mahn Joo Kim et al.
Current opinion in biotechnology, 13(6), 578-587 (2002-12-17)
The combination of enzyme and metal catalysis is described as a useful method for the synthesis of optically active compounds. A key feature of this new methodology is the use of metal catalysts for the in situ racemization of enzymatically

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