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Merck
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文件

514365

Sigma-Aldrich

乙酰丙酮酸铜

≥99.9% trace metals basis

别名:

2,4-戊二酮 铜(II) 衍生物, 2,4-戊二酮铜(II), Cu(acac)2, 乙酰丙酮铜

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About This Item

线性分子式:
Cu(C5H7O2)2
CAS号:
13395-16-9
分子量:
261.76
Beilstein:
4157957
EC號碼:
236-477-9
MDL號碼:
MFCD00000016
分類程式碼代碼:
12352103
PubChem物質ID:
24873754
NACRES:
NA.23

化驗

≥99.9% trace metals basis

形狀

powder

反應適用性

core: copper

mp

284-288 °C (dec.) (lit.)

SMILES 字串

CC(=O)\C=C(\C)O[Cu]O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.Cu/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;

InChI 密鑰

QYJPSWYYEKYVEJ-FDGPNNRMSA-L

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相关类别

一般說明

乙酰丙酮铜(II)是一种有机金属配位化合物，广泛用作多种有机反应（包括氧化、交叉偶联和聚合反应）的催化剂。它也是制造有机金属框架（MOF）和纳米材料的前体。

應用

乙酰丙酮铜(II)可用作：
  • 用于全氧化物光电池中氧化铜原子层沉积的前体。
  • 苯乙烯的氮丙啶化（aziridination） 催化剂。
  • Huisgen-Click反应合成1,2,3-三唑的催化剂。

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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Yi Wang et al.
Journal of medicinal chemistry, 56(23), 9601-9611 (2013-11-28)
Current precious-metal-containing anticancer agents are mostly chelated with N-containing ligands and function by interacting with DNA. In the present study, Pd(acac)2, a Pd(II) complex containing four O-donor ligands, has been evaluated as an active anticancer agent. Pd(acac)2 showed no interaction
Gong-Jun Chen et al.
Dalton transactions (Cambridge, England : 2003), 39(44), 10637-10643 (2010-10-06)
Two Eu(III) complexes, [Eu(acac)(3)(dpq)] (1) and [Eu(acac)(3)(dppz)] CH(3)OH (2) {viz. acetylacetonate (acac), dipyrido[3,2-d:20,30-f]quinoxaline (dpq), dipyrido[3,2-a:20,30-c] phenazine (dppz)}, have been synthesized and their DNA binding, photo-induced DNA cleavage activity and cell cytotoxicity are studied. The complexes display significant binding propensity to
The direct writing of plasmonic gold nanostructures by electron-beam-induced deposition.
Katja Höflich et al.
Advanced materials (Deerfield Beach, Fla.), 23(22-23), 2657-2661 (2011-05-04)
Channa R De Silva et al.
Journal of the American Chemical Society, 131(18), 6336-6337 (2009-04-17)
Nearly monodisperse lanthanide-doped magnetite nanoparticles were obtained by thermally decomposing a mixture of Fe(acac)(3) and Ln(acac)(3) (acac = acetylacetonate; Ln = Sm, Eu, Gd) in the presence of passivating surfactants. Magnetic studies revealed room-temperature ferromagnetic behaviors of these doped nanoparticles
Zhan'ao Tan et al.
Physical chemistry chemical physics : PCCP, 14(42), 14589-14595 (2012-09-28)
A solution-processed vanadium oxide (s-VO(x)) anode buffer layer on an indium-tin-oxide (ITO) electrode was used instead of PEDOT:PSS for improving the stability and photovoltaic performance of the polymer solar cells (PSCs). The s-VO(x) layer was prepared by spin-coating a vanadyl
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