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Merck

477567

Sigma-Aldrich

5,10,15,20-四(4-羟基苯基)-21H,23H-卟吩

Dye content 95 %

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About This Item

经验公式(希尔记法):
C44H30N4O4
CAS号:
分子量:
678.73
MDL號碼:
分類程式碼代碼:
12171500
PubChem物質ID:
NACRES:
NA.47

形狀

powder

品質等級

成份

Dye content, 95%

mp

>300 °C (lit.)

λmax

421 nm

&epsilon ;(消光係數)

≥285000 at 417-423 nm in methanol at 0.001 g/L

應用

diagnostic assay manufacturing
hematology
histology

儲存溫度

room temp

SMILES 字串

Oc1ccc(cc1)-c2c3ccc(n3)c(-c4ccc(O)cc4)c5ccc([nH]5)c(-c6ccc(O)cc6)c7ccc(n7)c(-c8ccc(O)cc8)c9ccc2[nH]9

InChI

1S/C44H30N4O4/c49-29-9-1-25(2-10-29)41-33-17-19-35(45-33)42(26-3-11-30(50)12-4-26)37-21-23-39(47-37)44(28-7-15-32(52)16-8-28)40-24-22-38(48-40)43(36-20-18-34(41)46-36)27-5-13-31(51)14-6-27/h1-24,45,48-52H/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-

InChI 密鑰

VFHDWGAEEDVVPD-LWQDQPMZSA-N

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一般說明

5,10,15,20-四(4-羟基苯基)-21H,23H-卟吩(TPPOH, 2H-OHTPP)是一种非手性卟啉衍生物。

應用

它可被用于制备基于卟啉的基质用于通过基质辅助激光解吸/电离(MALDI)质谱进行水溶性维生素的检测。它还可被用于制备5,10,15,20-四(4-聚乙烯氧基)苯基)卟啉。插入了2H-OHTPP的纳米多孔二氧化硅赋予了其气体敏感性,可用于通过表面等离子体共振检测NO2

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1A - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Detection of water?soluble vitamins by matrix?assisted laser desorption/ionization time?of?flight mass spectrometry using porphyrin matrices.
Chen YT and Ling YC
Journal of Mass Spectrometry : Jms, 37(7), 716-730 (2002)
Prunier ML
Catalysis of Organic Reactions null
Anna Synak et al.
The journal of physical chemistry. B, 114(49), 16567-16573 (2010-11-26)
The relaxation dynamics of 5,10,15,20-tetrakis(4-hydroxyphenyl)-porphyrin (p-THPP) in tetrahydrofuran (THF) and encapsulated within the human serum albumin (HSA) protein in water solution was investigated. The protein environment affects the B→Q(y) and Q(x)→Q(y) transition dynamics (from 80 and 140-200 fs in THF
Giovanna De Luca et al.
The journal of physical chemistry. B, 110(29), 14135-14141 (2006-07-21)
Acidification of tetrakis(4-hydroxyphenyl)porphyrin (THPP) and tetrakis(3,5-dihydroxyphenyl)porphyrin (OHPP) in dichloromethane solutions has been investigated as a function of the nature of the counteranion. These porphyrins exhibit different patterns of behavior, and extended aggregates are formed displaying broad extinction features together with
Yvette Niamien Konan et al.
European journal of pharmaceutical sciences : official journal of the European Federation for Pharmaceutical Sciences, 18(3-4), 241-249 (2003-03-28)
A photosensitizer, meso-tetra(hydroxyphenyl)porphyrin (p-THPP) was incorporated into sterile submicronic nanoparticles of poly(D,L-lactide-co-glycolide) (50:50 and 75:25 PLGA) and poly(D,L-lactide) (PLA). With all polymers used, sub-130 nm p-THPP-loaded nanoparticles with similar drug loadings and entrapment efficiencies were produced using the emulsification-diffusion technique.

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