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468517

Sigma-Aldrich

3,5-双(三氟甲基)苯基异硫氰酸酯

98%

别名:

1-异硫氰酸基-3,5-双（三氟甲基）苯

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About This Item

线性分子式:
(CF3)2C6H3NCS
CAS号:
23165-29-9
分子量:
271.18
MDL號碼:
MFCD00040838
分類程式碼代碼:
12352100
PubChem物質ID:
24870523
NACRES:
NA.22

品質等級

100

化驗

98%

折射率

n20/D 1.5 (lit.)

bp

63 °C/1.5 mmHg (lit.)

密度

1.485 g/mL at 25 °C (lit.)

官能基

fluoro
isothiocyanate

SMILES 字串

FC(F)(F)c1cc(cc(c1)C(F)(F)F)N=C=S

InChI

1S/C9H3F6NS/c10-8(11,12)5-1-6(9(13,14)15)3-7(2-5)16-4-17/h1-3H

InChI 密鑰

FXOSSGVJGGNASE-UHFFFAOYSA-N

相关类别

應用

3,5-双（三氟甲基）苯基异硫氰酸酯已用于以下研究：
  • 氨基官能化模型表面的化学衍生化，金上的氨基硫醇盐，硅上的氨基硅氧烷，以及聚乙烯（PE）箔和膜。
  • ω-氨基-4,4′-三联苯基取代的链烷硫醇的自组装单层的化学衍生化。
  • 乙烯基磺酰亚胺硫脲的合成。
  • 吡咯烷-2-羧酸-{2- [3-（3,5-双三氟甲基苯基）硫脲基]苯基}-酰胺的制备。

象形圖

Skull and crossbones
GHS06

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類（WGK）

WGK 3

閃點（°F）

228.2 °F - closed cup

閃點（°C）

109 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCQ7667
MKCM3351
MKCL9910
MKCJ8583
MKCH8496

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Paul M Dietrich et al.
Langmuir : the ACS journal of surfaces and colloids, 26(6), 3949-3954 (2010-01-01)
Amino-terminated self-assembled monolayers on gold substrates were studied by X-ray photoelectron spectroscopy (XPS), near-edge X-ray absorption fine structure (NEXAFS) measurements, and atomic force microscopy (AFM). Two different omega-amino-4,4'-terphenyl substituted alkanethiols of the general structure H(2)N-(C(6)H(4))(3)-(CH(2))(n)-SH (ATPn) were used: 2-(4''-amino-1,1':4',1''-terphenyl-4-yl)ethane-1-thiol (n
Highly diastereo-and enantioselective direct aldol reactions promoted by water-compatible organocatalysts bearing a pyrrolidinyl-camphor structural scaffold.
Tzeng Z-H, et al.
Tetrahedron, 65(5), 2879-2888 (2009)
Marcus Frings et al.
Beilstein journal of organic chemistry, 8, 1443-1451 (2012-09-29)
For the first time, chiral sulfoximine derivatives have been applied as asymmetric organocatalysts. In combination with a thiourea-type backbone the sulfonimidoyl moiety leads to organocatalysts showing good reactivity in the catalytic desymmetrization of a cyclic meso-anhydride and moderate enantioselectivity in
Nora Graf et al.
Analytical and bioanalytical chemistry, 396(2), 725-738 (2009-11-06)
The determination of amino groups on surfaces capable of binding biomolecules is important for the understanding and optimization of technologically relevant coupling processes. In this study, three different types of amino-functionalized model surfaces, amino thiolate on Au, amino siloxane on

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