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About This Item
经验公式（希尔记法）:
C5H12N2
CAS号:
分子量:
100.16
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:
NACRES:
NA.22
推荐产品
品質等級
化驗
97%
形狀
liquid
光學活性
[α]20/D +20°, c = 1 in chloroform
折射率
n20/D 1.482 (lit.)
bp
65 °C/11 mmHg (lit.)
密度
0.933 g/mL at 25 °C (lit.)
SMILES 字串
NC[C@@H]1CCCN1
InChI
1S/C5H12N2/c6-4-5-2-1-3-7-5/h5,7H,1-4,6H2/t5-/m0/s1
InChI 密鑰
AUKXFNABVHIUAC-YFKPBYRVSA-N
一般說明
(S)-(+)-2-(Aminomethyl)pyrrolidine is a chiral vicinal diamine.
應用
用于合成具有抗癌活性的化合物。
(S)-(+)-2-(Aminomethyl)pyrrolidine can be used as an organocatalyst:
It can also be used as a reactant to prepare Schiff base metal complexes with pyrrolidine fragment as a ligand in asymmetric synthesis.
- For the asymmetric transformation of (S)-alanine.
- In the asymmetric α-fluorination of linear and branched aldehydes using N-fluorobenzenesulfonamide as the fluorinating agent.
It can also be used as a reactant to prepare Schiff base metal complexes with pyrrolidine fragment as a ligand in asymmetric synthesis.
訊號詞
Warning
危險分類
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
116.6 °F - closed cup
閃點（°C）
47 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
K Morikawa et al.
Journal of pharmaceutical sciences, 80(9), 837-842 (1991-09-01)
The optical isomers of 2-aminomethylpyrrolidine(1,1-cyclobutane- dicarboxylato)platinum(II) (DWA2114, 1), which has potent antitumor activity against various tumors, were synthesized. They were examined for antitumor activity against Colon 26 carcinoma in a sc-iv system, and changes in urinary protein and sugar levels
Dioxovanadium (V) complexes of Schiff bases derived from S-(+)-2-(aminomethyl) pyrrolidine and aromatic o-hydroxycarbonyl compounds: Synthesis, characterization and structure
Kwiatkowski E, et al.
Polyhedron, 25(15), 2809-2814 (2006)
商品
Chiral vicinal diamines are of tremendous interest to the synthetic chemist as they are found in many chiral catalysts and pharmaceuticals.
Chiral vicinal diamines are of tremendous interest to the synthetic chemist as they are found in many chiral catalysts and pharmaceuticals.
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