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Merck

377538

Sigma-Aldrich

正庚基三苯基溴化磷

97%

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About This Item

线性分子式:
CH3(CH2)6P(C6H5)3Br
CAS号:
分子量:
441.38
EC號碼:
MDL號碼:
分類程式碼代碼:
12352002
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

97%

反應適用性

reaction type: C-C Bond Formation

mp

173-176 °C (lit.)

SMILES 字串

[Br-].CCCCCCC[P+](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C25H30P.BrH/c1-2-3-4-5-15-22-26(23-16-9-6-10-17-23,24-18-11-7-12-19-24)25-20-13-8-14-21-25;/h6-14,16-21H,2-5,15,22H2,1H3;1H/q+1;/p-1

InChI 密鑰

WCZSOHSGMBVYFW-UHFFFAOYSA-M

應用

Reactant for:
  • Stereospecific rearrangement of epoxides to quaternary carbaldehydes
  • Synthesis of the male pheromone of two species of termite Zootermopsis
  • Regio- and stereoselective TEMPO oxidation
  • Diastereoselective synthesis of climacostol for antitumor activity
  • Enantioselective synthesis of chiral vinylphosphonate and phosphonate analogs of immunosuppressive agent FTY720
  • Preparation of embelin derivatives with XIAP inhibitory and anticancer activity

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Darya A Kuznetsova et al.
Journal of materials chemistry. B, 7(46), 7351-7362 (2019-11-07)
The purpose of this work was to obtain cationic liposomes based on 1,2-dipalmitoyl-sn-glycero-3-phosphocholine noncovalently modified using alkyltriphenylphosphonium bromides (TPPB-n) with different lengths of hydrocarbon tail for targeted delivery to mitochondria. The hydrodynamic diameter and electrokinetic potential of hybrid liposomes depending
Tejia Zhang et al.
Journal of lipid research, 56(8), 1501-1510 (2015-06-11)
Apoptosis is an intricately regulated cellular process that proceeds through different cell type- and signal-dependent pathways. In the mitochondrial apoptotic program, mitochondrial outer membrane permeabilization by BCL-2 proteins leads to the release of apoptogenic factors, caspase activation, and cell death.

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