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Merck

374598

Sigma-Aldrich

十六烷基三甲基硫酸氢铵

99%

别名:

CTAHSO4, Hexadecyltrimethylammonium hydrogen sulfate

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About This Item

线性分子式:
CH3(CH2)15N(HSO4)(CH3)3
CAS号:
分子量:
381.61
EC號碼:
MDL號碼:
分類程式碼代碼:
12352107
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

99%

mp

250-260 °C (dec.) (lit.)

SMILES 字串

OS([O-])(=O)=O.CCCCCCCCCCCCCCCC[N+](C)(C)C

InChI

1S/C19H42N.H2O4S/c1-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19-20(2,3)4;1-5(2,3)4/h5-19H2,1-4H3;(H2,1,2,3,4)/q+1;/p-1

InChI 密鑰

UCRJJNVFJGKYQT-UHFFFAOYSA-M

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應用

十六烷基三甲基硫酸氢铵常作为表面活性剂用于水介质中的有机转化反应。
应用示例:
  • 铑(I)-催化的(Z)-甲基-α-乙酰氨基肉桂酸盐的不对称氢化反应。
  • 钯催化的1,3-二苯基-2-丙烯乙酸盐与二甲基丙二酸盐的不对称烷化反应。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Catalytic asymmetric alkylation in water in the presence of surfactants
Sinou D, et al.
advanced synthesis and catalysis, 345(3), 357-363 (2003)
Influence of different types of amphiphiles on the rhodium (I) complex-catalyzed asymmetric hydrogenation of (Z)-methyl-α-acetamidocinnamate in aqueous medium
Grassert I, et al.
Tetrahedron, 49(30), 6605-6612 (1993)
Micellar effects upon oxidation of organic sulfides by anionic oxidants
Bacaloglu R, et al.
Journal of Physical Organic Chemistry, 5(4), 171-178 (1992)
Ahmet Gürses et al.
TheScientificWorldJournal, 2012, 270452-270452 (2013-02-01)
The aim of this study was the preparation of polyethylene oxide (PEO)/clay nanocomposites using organoclay produced via micellar adsorption of cethyltrimethyl ammonium bromide (CTAB) and their characterisation by X-ray diffraction (XRD), and Fourier transform infrared (FT-IR) spectra, and the investigation
Lin Wang et al.
Journal of hazardous materials, 244-245, 681-688 (2012-11-28)
Photocatalytic reduction of aqueous Cr(VI) was successfully achieved on nanostructured SnIn(4)S(8). The SnIn(4)S(8) particles with flower-like nanostructure were synthesized via a facile solvothermal method. UV-vis diffuse reflectance spectra (DRS) indicated that the SnIn(4)S(8) particles had strong absorption in visible region

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