373567

亚硝酰硝酸钌(III) 溶液

in dilute nitric acid

• 别名: Nitrilooxonium ruthenium(2+) nitrate (1:1:3)
• 线性分子式: Ru(NO)(NO₃)_x(OH)_y, x+y=3
• CAS号: 34513-98-9
• 分子量: 318.10
• MDL號碼: MFCD00016313
• 分類程式碼代碼: 12352302
• PubChem物質ID: 24863244
• NACRES: NA.23

属性

• 形狀: liquid
• 品質等級: 100
• 成份: Ru, 1.5% (typical)
• 反應適用性: reagent type: catalyst; core: ruthenium
• 濃度: in dilute nitric acid
• 密度: 1.07 g/mL at 25 °C
• SMILES 字串: [Ru+3]N=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
• InChI: 1S/3NO3.NO.Ru/c3*2-1(3)4;1-2;/q4*-1;+4
• InChI 密鑰: VAAILMLOAHTPQK-UHFFFAOYSA-N

说明

一般說明

Ruthenium(III) nitrosyl nitrate solution is a stable and water-soluble compound. The presence of the nitrosyl ligand contributes to its distinct reactivity and coordination behavior. Additionally, the compound exhibits characteristic spectroscopic properties that make it valuable in analytical and research applications.

應用

Ruthenium(III) nitrosyl nitrate solution can be used:

• As a Ru source to prepare Y₂Ru₂O₇/NiMoO₄@NF electrocatalyst by a combined sol–gel and hydrothermal method, which exhibits superior stability for overall water splitting in an alkaline medium.
• To fabricate bifunctional electrode for Li-air batteries.
• As a precursor to synthesize ruthenium nanoparticles with variable sizes. It helps to form stable ruthenium nitrite complex avoiding the unwanted metal oxide hydrolysis or precipitation.

安全信息

• 象形圖: GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H290,H314,H332
• 防範說明: P234 - P261 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• 危險分類: Acute Tox. 4 Inhalation - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A
• 安全危害: EUH071
• 儲存類別代碼: 8B - Non-combustible corrosive hazardous materials
• 水污染物質分類（WGK）: WGK 1
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter