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364789

Sigma-Aldrich

叔丁基 2,2,2-三氯乙酰亚胺酯

96%

别名:

TBTA

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About This Item

线性分子式:
CCl3C(=NH)OC(CH3)3
CAS号:
98946-18-0
分子量:
218.51
Beilstein:
1770049
MDL號碼:
MFCD00077410
分類程式碼代碼:
12352100
PubChem物質ID:
24862454
NACRES:
NA.22

品質等級

200

化驗

96%

折射率

n20/D 1.456 (lit.)

bp

65 °C/11 mmHg (lit.)

mp

21 °C (lit.)

密度

1.221 g/mL at 25 °C (lit.)

官能基

chloro
ether

儲存溫度

2-8°C

SMILES 字串

CC(C)(C)OC(=N)C(Cl)(Cl)Cl

InChI

1S/C6H10Cl3NO/c1-5(2,3)11-4(10)6(7,8)9/h10H,1-3H3

InChI 密鑰

CQXDYHPBXDZWBA-UHFFFAOYSA-N

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應用

2,2,2-三氯乙酰亚胺叔丁酯可用于合成N-α-Fmoc-磷酸（1-硝基苯基乙基-2-氰基乙基）-L-丝氨酸，笼状结构单元。它可用于将醇和羧酸转化为它们各自的醚和酯。

象形圖

FlameExclamation mark
GHS02,GHS07

訊號詞

Warning

危險分類

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

131.0 °F - closed cup

閃點（°C）

55 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCD9267
BCBV8062
BCBR4658V
BCBN0897V
BCBM1820V

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Journal of the Chemical Society. Perkin Transactions 1, 2247-2247 (1985)
Deborah M Rothman et al.
The Journal of organic chemistry, 68(17), 6795-6798 (2003-08-16)
Three 1-(2-nitrophenyl)ethyl-caged phospho-amino acids have been synthesized for use in standard N(alpha)-fluorenylmethoxycarbonyl-based solid-phase peptide synthesis (SPPS). The most common naturally occurring phospho-amino acids, serine, threonine, and tyrosine, were prepared as protected caged building blocks by modification with a unique phosphitylating
Maiyun Yang et al.
Nature communications, 5, 4981-4981 (2014-09-23)
Bioorthogonal reactions, especially the Cu(I)-catalysed azide-alkyne cycloaddition, have revolutionized our ability to label and manipulate biomolecules under living conditions. The cytotoxicity of Cu(I) ions, however, has hindered the application of this reaction in the internal space of living cells. By
Brett J Roberts et al.
Journal of cell science, 127(Pt 17), 3782-3793 (2014-07-09)
Desmosomes are prominent adhesive junctions found in various epithelial tissues. The cytoplasmic domains of desmosomal cadherins interact with a host of desmosomal plaque proteins, including plakophilins, plakoglobin and desmoplakin, which, in turn, recruit the intermediate filament cytoskeleton to sites of

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