349925

(+)-氯甲基薄荷醚

97%

• 经验公式（希尔记法）: C₁₁H₂₁ClO
• CAS号: 103128-76-3
• 分子量: 204.74
• MDL號碼: MFCD09039273
• 分類程式碼代碼: 12352101
• PubChem物質ID: 24861717
• NACRES: NA.22

属性

• 化驗: 97%
• 形狀: liquid
• 光學活性: [α]24/D +181.0°, c = 2 in methylene chloride
• 光學純度: ee: 98% (GLC)
• 折射率: n20/D 1.467 (lit.)
• bp: 72 °C/0.4 mmHg (lit.)
• 密度: 0.994 g/mL at 25 °C (lit.)
• 儲存溫度: −20°C
• SMILES 字串: CC(C)[C@H]1CC[C@H](C)C[C@@H]1OCCl
• InChI: 1S/C11H21ClO/c1-8(2)10-5-4-9(3)6-11(10)13-7-12/h8-11H,4-7H2,1-3H3/t9-,10+,11-/m0/s1
• InChI 密鑰: XOPLTFUYFXWFGB-AXFHLTTASA-N

说明

應用

(+)-Chloromethyl menthyl ether can be used:

• As a starting material for the synthesis of 1-methyl-3-(+)-methylmenthoxide imidazolium chloride, a key intermediate for the preparation of Ag(I) N-heterocyclic carbene, applicable as a catalyst in the diboration of alkenes.
• As a substrate in the synthesis of commercially important O-substituted α-methoxymethylketones.
• To determine enantiomeric excess (ee) of an iron chiral auxiliary named [Fe(CO)(η;⁵- C₂H₅)(PPh₃)COCH₃].

安全信息

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 10 - Combustible liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 224.6 °F - closed cup
• 閃點（°C）: 107 °C - closed cup
• 個人防護裝備: Eyeshields, Gloves, type ABEK (EN14387) respirator filter