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Merck

341169

Sigma-Aldrich

酞菁锌

Dye content 97 %

别名:

酞菁 锌盐

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About This Item

经验公式(希尔记法):
C32H16N8Zn
CAS号:
分子量:
577.91
Beilstein:
4121852
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.23

成份

Dye content, 97%

品質等級

反應適用性

reagent type: catalyst
core: zinc

λmax

701 nm

軌道能量

HOMO 5.17 eV (CV)
LUMO 3.78 eV (CV)

OPV器件效能

ITO/ZnPc:P60 (1:1)/Bphen/Ag

  • Short-circuit current density (Jsc): 11.7 mA/cm2
  • Open-circuit voltage (Voc): 0.54 V
  • Fill Factor (FF): 0.62
  • Power Conversion Efficiency (PCE): 3.9 %

SMILES 字串

[Zn]1n2c3nc4nc(nc5n1c(nc6nc(nc2c7ccccc37)c8ccccc68)c9ccccc59)c%10ccccc4%10

InChI

1S/C32H16N8.Zn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2

InChI 密鑰

PODBBOVVOGJETB-UHFFFAOYSA-N

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一般說明

锌(II)酞菁(ZnPc)配合物具有光敏性。酞菁具有显著的π-π相互作用,易于形成H聚集体。

應用

锌酞菁在工业(催化剂、光电导体等)和生物医学(光动力疗法,PDT)中具有普遍应用。ZnPc可用于光氧化环己烷。 一项研究报告了用ZnPc对聚合物膜进行功能化。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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Ye-Liang Wang et al.
Chimia, 66(1-2), 31-37 (2012-05-02)
We report on high-resolution STM measurements with modified probe tips. First, both the rest atoms and adatoms of a Si(111)-7×7 surface are observed simultaneously. The visibility of rest atoms is dependent upon the sample bias voltage (less than -0.7 V)
Anamika Ray et al.
The journal of physical chemistry. B, 116(39), 11979-11998 (2012-08-23)
The present article reports photophysical studies on supramolecular interaction of a zinc phthalocyanine derivative, namely, zinc-2,9,16,23-tetra-tert-butyl phthalocyanine (1) with C(60) and C(70) in solvents having varying polarity, i.e., toluene and 1,2-dichlorobenzene (DCB). The interesting feature of the present work is
Effect of blend layer morphology on performance of ZnPc:C60-based photovoltaic cells
Zeng, W.; et al.
Applied Physics Letters, 97, 133304-133304 (2010)
Thandekile P Mthethwa et al.
Dalton transactions (Cambridge, England : 2003), 42(14), 4922-4930 (2013-02-07)
A novel thiol functionalized zinc phthalocyanine complex (ZnPcSH) is reported in this work. This complex was conjugated to gold nanoparticles. The photophysical and photochemical properties of the complex and the conjugate were investigated. Upon conjugation a blue shift was observed
Sean Marrache et al.
Integrative biology : quantitative biosciences from nano to macro, 5(1), 215-223 (2012-07-27)
A therapeutic technology that combines the phototoxic and immune-stimulating ability of photodynamic therapy (PDT) with the widespread effectiveness of the immune system can be very promising to treat metastatic breast cancer. We speculated that the knowledge of molecular mechanisms of

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