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品質等級
化驗
99%
形狀
powder
反應適用性
core: bismuth
reagent type: catalyst
mp
408 °C (lit.)
密度
5.78 g/mL at 25 °C (lit.)
SMILES 字串
I[Bi](I)I
InChI
1S/Bi.3HI/h;3*1H/q+3;;;/p-3
InChI 密鑰
KOECRLKKXSXCPB-UHFFFAOYSA-K
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應用
碘化铋(III)或三碘化铋无毒性,因此可作为环保催化剂使用。它可用作以下反应的催化剂:
- 水中的缩醛和缩酮的化学选择性脱保护反应。
- 硫脲和胺合成多取代胍的成胍反应。
- 羰基化合物的巯基化反应。
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
其他客户在看
Bismuth (III) Halides and Sulfate as Highly Efficient Catalyst for the Sulfenylation of Carbonyl and Related Compounds1
Komatsu N, et al.
Synlett, 1995(09), 984-986 (1995)
The first bismuth (III)-catalyzed guanylation of thioureas
Cunha S and Rodrigues Jr MT
Tetrahedron Letters, 47(39), 6955-6956 (2006)
Environmentally friendly organic synthesis using bismuth compounds: bismuth (III) iodide catalyzed deprotection of acetals in water
Bailey AD, et al.
Tetrahedron Letters, 49(4), 691-694 (2008)
Wenhua Bi et al.
Chemical communications (Cambridge, England), (44)(44), 5743-5745 (2008-11-15)
The dehydration of a iodobismuthate hybrid built up from Bi(4)I(16) clusters and protonated L-cystine molecules involves an unprecedented reversible dynamic structural change in the solid state leading to 1D BiI(4) chains and 1D helical molecular chains, highlighting the templating effect
Jie Sun et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 79(5), 904-908 (2011-05-10)
A novel series of Ge-Te-BiI(3) chalcogenide glasses were prepared by traditional melt-quenching method and the glass-forming region was determined. Properties measurements including density, Vis-NIR and infrared (IR) transmission spectra with FTIR, XRD, DSC were adopted to analyze the composition, structure
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