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Merck

332828

Sigma-Aldrich

2-丁酮肟

99%

别名:

甲乙酮肟

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About This Item

线性分子式:
C2H5C(=NOH)CH3
CAS号:
分子量:
87.12
Beilstein:
1698241
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

3 (vs air)

品質等級

蒸汽壓力

<8 mmHg ( 20 °C)

化驗

99%

形狀

liquid

折射率

n20/D 1.442 (lit.)

bp

59-60 °C/15 mmHg (lit.)

溶解度

water: soluble 100 g/L at 25 °C

密度

0.924 g/mL at 25 °C (lit.)

官能基

amine
oxime

SMILES 字串

CC\C(C)=N\O

InChI

1S/C4H9NO/c1-3-4(2)5-6/h6H,3H2,1-2H3/b5-4+

InChI 密鑰

WHIVNJATOVLWBW-SNAWJCMRSA-N

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一般說明

丁酮肟是一种抗氧化剂和封闭剂,用于合成水分散性封闭聚氨酯( blocked polyurethane)。

應用

以 2-丁酮肟为试剂和溶剂,合成了酮亚胺和 2,4-二吡啶-1,3,5-三氮杂戊二烯钯 (II) 配合物。它也用于合成新型的乙缩醛二亚胺钴配合物,[CoI2{((CH3CH2)(CH3)C=NO)2C(CH3)2}]。

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Carc. 1B - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 - STOT SE 1 - STOT SE 3

標靶器官

Blood, Central nervous system, Upper respiratory tract

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

143.5 °F - closed cup

閃點(°C)

61.97 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析证书(COA)

Lot/Batch Number

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Michael J Derelanko et al.
Drug and chemical toxicology, 26(3), 147-168 (2003-09-05)
The developmental toxicity of methyl ethyl ketoxime (MEKO), an industrial antioxidant used primarily as an antiskinning agent in alkyd paint, was investigated in rats and rabbits. Following preliminary dose range finding studies, groups of 25 pregnant rats or 18 pregnant
R W Tyl et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 31(2), 149-161 (1996-06-01)
Methylethyl ketoxime (CAS No. 96-29-7; MEKO; 2-butanone oxime), an antioxidant agent used in paints, resins, and adhesives, was tested for reproductive toxicity in a two-generation study with CD (Sprague-Dawley) rats. Thirty-eight-week-old rats/sex/group (F0) were administered MEKO in water, by gavage
Michael J Derelanko et al.
Drug and chemical toxicology, 31(1), 97-114 (2007-12-29)
Acute and repeated oral and dermal rat toxicology studies of standard designs were conducted on four methyl ethyl ketoxime (MEKO) silanes and four methyl isobutyl ketoxime (MIBKO) silanes. Each compound contained either MEKO or MIBKO groups (but not both) and
Paul E Newton et al.
Inhalation toxicology, 14(12), 1249-1260 (2002-11-28)
Methylethylketoxime, also known as MEKO or 2-butanone oxime (CAS No. 96-29-7), is a clear, colorless to light yellow liquid at room temperature. It is an industrial antioxidant used as an antiskinning agent in alkyd paint, an industrial blocking agent for
L T Burka et al.
Xenobiotica; the fate of foreign compounds in biological systems, 28(10), 1005-1015 (1998-12-16)
1. The disposition of 14C-methyl ethyl ketoxime (MEKO) was determined in the male F344 rat following oral, intravenous (i.v.) and dermal administration. 2. Oral doses of 2.7, 27 and 270 mg/kg were primarily excreted as CO2 (71-49%) in decreasing percentage

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