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302163

(R)-(-)-1-苯基-1,2-乙二醇

Name: (<I>R</I>)-(-)-1-苯基-1,2-乙二醇
Brand: ALDRICH

99%

别名:

(-)-苯乙二醇, (R)-(-)-苯基乙二醇

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About This Item

线性分子式:

HOCH₂CH(C₆H₅)OH

CAS号:

16355-00-3

分子量:

138.16

Beilstein:

2355547

MDL號碼:

MFCD00064262

分類程式碼代碼:

12352002

PubChem物質ID:

24858238

NACRES:

NA.22

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Sigma-Aldrich

115568

(S)-(-)-α-甲基苄胺

化驗

99%

光學活性

[α]20/D −69°, c = 1 in chloroform

bp

272-274 °C (lit.)

mp

64-67 °C (lit.)

官能基

hydroxyl
phenyl

SMILES 字串

OC[C@H](O)c1ccccc1

InChI

1S/C8H10O2/c9-6-8(10)7-4-2-1-3-5-7/h1-5,8-10H,6H2/t8-/m0/s1

InChI 密鑰

PWMWNFMRSKOCEY-QMMMGPOBSA-N

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應用

合成不对称氢化反应的手性膦催化剂时所用的中间体。

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)

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分析证书(COA)

Lot/Batch Number

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J. Chem. Soc. Perkin Trans. II, 489-489 (1982)

The Journal of Organic Chemistry, 44, 1729-1729 (1979)

Simultaneous determination of phenylglyoxylic acid, mandelic acid, styrene glycol and hippuric acid in primary culture of rat hepatocytes incubate by high-performance liquid chromatography.

Jin-Zhao Wang et al.

Biomedical chromatography : BMC, 21(5), 497-501 (2007-03-16)

A simple HPLC method for the simultaneous determination of phenylglyoxylic acid (PGA), mandelic acid (MA), styrene glycol (SG) and hippuric acid (HA) in cell culture medium was developed. Analysis was performed on a C(18) column with a mobile phase composed

[Construction of an enzyme-coupled system consisting of (R)- and (S)-specific carbonyl reductases for one-step preparation of (S)-1-phenyl-1,2-ethanediol].

Rongzhen Zhang et al.

Wei sheng wu xue bao = Acta microbiologica Sinica, 49(2), 204-209 (2009-05-19)

To prepare (S)-1-phenyl-1,2-ethanediol by a one-step method, we constructed an enzyme coupled system consisting of (R)- and (S)-specific carbonyl reductases in Escherichia coli. The genes coding (R)- and (S)-specific carbonyl reductases from Candida parapsilosis were inserted into a co-expression vector

Enhancement of Candida parapsilosis catalyzing deracemization of (R,S)-1-phenyl-1,2-ethanediol to its (S)-enantiomer by a highly productive "two-in-one" resin-based in situ product removal strategy.

Qingsen Hu et al.

Bioresource technology, 101(21), 8461-8463 (2010-06-25)

In this study, a highly efficient process for Candida parapsilosis-catalyzed deracemization of racemic 1-phenyl-1,2-ethanediol (PED) was described, based on a resin-based in situ substrate feeding and product removal (ISSFPR) methodology. The resin H103 was selected and used to keep the

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