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Merck

294861

Sigma-Aldrich

1-氯金刚烷

98%

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About This Item

经验公式(希尔记法):
C10H15Cl
CAS号:
分子量:
170.68
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

形狀

solid

mp

165-166 °C (lit.)

官能基

chloro

SMILES 字串

ClC12C[C@H]3C[C@H](C[C@H](C3)C1)C2

InChI

1S/C10H15Cl/c11-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9H,1-6H2/t7-,8+,9-,10-

InChI 密鑰

OZNXTQSXSHODFR-CHIWXEEVSA-N

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一般說明

An unusual zwitterionic diradical intermediate complex was generated during the photoinduced electron-transfer substitution reaction between 1-chloroadamantane and tert-butylamine system in a hydrocarbon glass.

應用

1-Chloroadamantane was employed as precursor for the synthesis of perfluoroadmantane derivatives via aerosol direct fluorination.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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分析证书(COA)

Lot/Batch Number

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Xue Li et al.
Journal of pharmaceutical sciences, 106(1), 395-401 (2016-11-07)
Supramolecular cyclodextrin-based nanoparticles (CD-NPs) mediated by host-guest interactions have gained increased popularity because of their "green" and simple preparation procedure, as well as their versatility in terms of inclusion of active molecules. Herein, we showed that original CD-NPs of around
John B Miller et al.
Journal of the American Chemical Society, 126(40), 12742-12743 (2004-10-08)
An unusual zwitterionic diradical intermediate complex R*...X-...HR'B*+ is generated during the photoinduced electron-transfer substitution reaction between alkyl halides (RX) and Lewis bases (HR'B). This reaction intermediate was observed for the 1-chloroadamantane and tert-butylamine system in a hydrocarbon glass at 25
Aerosol fluorination of 1-chloroadamantane, 2-chloroadamantane, and methyl 1-adamantylacetate: a novel synthetic approach to 1-and 2-substituted hydryl-, methyl-, and (difluoromethyl-F-adamantanes.
Adcock JL, et al.
The Journal of Organic Chemistry, 57(17), 4749-4752 (1992)

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