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Merck

241024

Sigma-Aldrich

磷酸三甲酯

≥99%

别名:

TMP, TMPA, TMPO

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About This Item

线性分子式:
(CH3O)3PO
CAS号:
分子量:
140.07
Beilstein:
1071731
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

≥99%

形狀

liquid

折射率

n20/D 1.395 (lit.)

bp

197 °C (lit.)

mp

−46 °C (lit.)

密度

1.197 g/mL at 25 °C (lit.)

官能基

phosphate

SMILES 字串

COP(=O)(OC)OC

InChI

1S/C3H9O4P/c1-5-8(4,6-2)7-3/h1-3H3

InChI 密鑰

WVLBCYQITXONBZ-UHFFFAOYSA-N

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一般說明

环境水中的磷酸三甲酯水平可通过直接分析实时电离源来确定,该电离源与具有多反应监测(MRM)的三重四极杆质谱仪(DART-MS/MS)连接

應用


  • 提高电池性能:磷酸三甲酯用于调节双盐包聚合物(polymer-in-dual-salt)电解质的离子导电性和界面相容性,显著扩大准固态金属电池的工作温度范围(Lin et al., 2024)。

  • 热化学性质分析:研究磷酸三甲酯的热化学性质和速率动力学,尤其是脱氢反应,提供宝贵的稳定性和反应性数据,对于各种化学合成应用有重要参考性(Bruce and Li, 2023)。

  • 有机磷阻燃剂检测:磷酸三甲酯用于筛查食品样品(特别是大米)中的有机磷阻燃剂残留,利用先进的色谱技术保证食品安全性和环境监管合规性(Li et al., 2023)。

  • 电池中的界面反应调控:通过电解质化学调节界面反应(涉及磷酸三甲酯),通过构筑低温锌金属电池的梯度界面相提高电池安全性和效率(Wang et al., 2023)。

象形圖

Health hazardExclamation mark

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Muta. 1B - Skin Irrit. 2

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 1

閃點(°F)

302.0 °F - closed cup

閃點(°C)

150 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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其他客户在看

Xiaowei Wang et al.
Journal of chromatography. A, 1333, 134-137 (2014-02-20)
Trimethyl phosphate (TMP) is used extensively in industrial chemical processes. Due to the high polarity and volatility, methods for its quantification in environmental samples have not been well developed. Currently, the pollution status of TMP in the environment still has
Marianna Ambrico et al.
Physical chemistry chemical physics : PCCP, 21(23), 12380-12388 (2019-05-30)
Nanoscale disassembly of mussel-inspired polydopamine (PDA) in ionic liquids (ILs) was recently shown to induce an electron paramagnetic resonance (EPR)-detectable reorganization of free radical centers in the resulting nanoparticles (NPs) in an IL-controlled manner. Herein, we report electrical impedance spectroscopy
Qingguo Meng et al.
Environmental science & technology, 45(7), 3000-3005 (2011-03-03)
Due to the neurotoxicity of organophosphate (OP) pesticides and nerve agents synthesized as military or terror agents, their safe destruction and disposal is of considerable current importance. A representative OP, trimethyl phosphate (TMP), was adsorbed onto NaX zeolite, two mesoporous
Johannes Bernarding et al.
Journal of the American Chemical Society, 128(3), 714-715 (2006-01-19)
In ultralow magnetic fields, liquid state nuclear magnetic resonance (NMR) spectra of homonuclear spin systems exhibit line widths dominated by their natural lifetime. Chemical shifts become negligible, and heteronuclear NMR spectra show predominantly the electron-mediated field-independent J-coupling. However, weak polarization
Chunhai Ruan et al.
Journal of the American Society for Mass Spectrometry, 19(2), 305-314 (2008-04-15)
Threshold collision-induced dissociation techniques are employed to determine the bond dissociation energies (BDEs) of complexes of alkali metal cations to trimethyl phosphate, TMP. Endothermic loss of the intact TMP ligand is the only dissociation pathway observed for all complexes. Theoretical

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