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238325

Sigma-Aldrich

烯丙基碘

98%

别名:

3-碘-1-丙烯

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About This Item

线性分子式:
CH2=CHCH2I
CAS号:
556-56-9
分子量:
167.98
Beilstein:
1697594
EC號碼:
209-130-4
MDL號碼:
MFCD00001094
分類程式碼代碼:
12352100
PubChem物質ID:
24854295
NACRES:
NA.22

化驗

98%

形狀

liquid

包含

copper as stabilizer

折射率

n20/D 1.554 (lit.)

bp

102-103 °C (lit.)

溶解度

alcohol: miscible(lit.)
chloroform: miscible(lit.)
diethyl ether: miscible(lit.)
water: insoluble (practically)(lit.)

密度

1.837 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

ICC=C

InChI

1S/C3H5I/c1-2-3-4/h2H,1,3H2

InChI 密鑰

HFEHLDPGIKPNKL-UHFFFAOYSA-N

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相关类别

一般說明

研究了在 270～480℃ 温度范围内，烯丙基碘化物与 MoO3, Bi2O3和 Bi、Co、Mg 的钼酸盐的相互作用。

應用

使用的烯丙基碘为：
  • 气相色谱法研究烯丙基化合物在单脉冲激波管中的复合
  • 在环丙烯的顺式-双烯丙基化反应中与烯丙基倍半碘化钠配合使用的试剂

訊號詞

Danger

危險聲明

H225,H300,H314

危險分類

Acute Tox. 2 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 1

閃點（°F）

60.8 °F - closed cup

閃點（°C）

16 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Interaction of allyl iodide with molybdate catalysts for the selective oxidation of hydrocarbons.
Grzybowska B, et al.
J. Catal., 49(2), 150-163 (1977)
Aleksandr Fridlyand et al.
The journal of physical chemistry. A, 117(23), 4762-4776 (2013-05-18)
The recombination and disproportionation of allyl radicals has been studied in a single pulse shock tube with gas chromatographic measurements at 1-10 bar, 650-1300 K, and 1.4-2 ms reaction times. 1,5-Hexadiene and allyl iodide were used as precursors. Simulation of
Tsunehisa Hirashita et al.
Organic & biomolecular chemistry, 5(13), 2154-2158 (2007-06-22)
The successive double allylation of cyclopropenes with allylindium sesquiiodide and allyl iodide proceeded with a cis-addition mode in the presence of other organometallics (e.g. Grignard reagent, cuprate, Et(2)Zn and Et(3)Al), giving the corresponding cis-diallylcyclopropanes in high yields.
Xin Ma et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(25), 6355-6361 (2019-02-28)
Unexpectedly, the 5-dehydroquinoline radical cation was formed in the gas phase from the 5-iodo-8-nitroquinolinium cation upon ion-trap collision-activated dissociation. This reaction involves the cleavage of a nitro group to generate an intermediate monoradical, namely, the 8-dehydro-5-iodoquinolinium cation, followed by rearrangement
Michael Lesslie et al.
European journal of mass spectrometry (Chichester, England), 21(3), 589-597 (2015-08-27)
Radical migration, both intramolecular and intermolecular, from the tyrosine phenoxyl radical Tyr(O(∙)) to the cysteine radical Cys(S(∙)) in model peptide systems was observed in the gas phase. Ion-molecule reactions (IMRs) between the radical cation of homotyrosine and propyl thiol resulted

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