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品質等級
化驗
≥99.0% (sum of enantiomers, GC)
形狀
solid
光學活性
[α]20/D +10.5±1°, c = 5% in chloroform
bp
273 °C (lit.)
mp
82-86 °C
86-87 °C (lit.)
官能基
hydroxyl
SMILES 字串
C[C@@H]1CC[C@H]2C(C)(C)[C@H]3C[C@@]12CC[C@@]3(C)O
InChI
1S/C15H26O/c1-10-5-6-11-13(2,3)12-9-15(10,11)8-7-14(12,4)16/h10-12,16H,5-9H2,1-4H3/t10-,11+,12-,14-,15+/m1/s1
InChI 密鑰
SVURIXNDRWRAFU-OGMFBOKVSA-N
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一般說明
(+)-雪松醇是α-雪松烯的结晶水合产物,雪松烯是雪松木油中发现的倍半萜烯。它可以用作化妆品,洗发水和肥皂中的香料成分,也可以用作非化妆品,例如清洁剂和洗涤剂。(±)雪松醇可以通过烷基环戊二烯的分子内Diels-Alder反应合成。
應用
(+)-雪松醇可用作在酸催化剂存在下使用乙酸酐乙酰化制备乙酸雪松酯的起始原料。它也可以作为通过选择性C-H键官能化全合成稀有八角倍半萜(+)-假茴香苷的前体掺入。
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 2
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
Journal of the American Chemical Society, 138(51), 16616-16619 (2016-12-15)
Illicium sesquiterpenes have been the subject of numerous synthetic efforts due to their ornate and highly oxidized structures as well as significant biological activities. Herein we report the first chemical synthesis of (+)-pseudoanisatin from the abundant feedstock chemical cedrol (∼$50
BMC infectious diseases, 19(1), 800-800 (2019-09-13)
Larviciding is an effective supplementary tool for malaria vector control, but the identification and accessibility of aquatic habitats impedes application. Dissemination of the insect growth regulator, pyriproxyfen (PPF), by gravid Anopheles might constitute a novel application strategy. This study aimed
Catalytic acetylation of (+)-cedrol with heterogeneous catalyst H2SO4/SiO2 under solvent free conditions
Chemical Intermediates, 1(4), 196-201 (2015)
Organic letters, 6(15), 2535-2538 (2004-07-17)
[reaction: see text] A short and convenient diastereoselective synthesis of all-carbon spirocylic molecules was developed. A straightforward protocol that involves rearrangement of the diene-Fe(CO)(3) complex followed by cyclization delivers the desired product. The reaction substrates were easily prepared by reaction
British journal of clinical pharmacology, 65(2), 188-196 (2007-10-24)
Relationships between smell sensation and autonomic changes have been studied extensively. However, the possibility that odorants may also act on the lung and lower airway remains unknown. The present results provide the first evidence that the lung and lower airway
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