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Merck
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文件

189316

Sigma-Aldrich

3-氯-2,2-二甲基-1-丙醇

99%

别名:

2-氯甲基-2-甲基-1-丙醇

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About This Item

线性分子式:
ClCH2C(CH3)2CH2OH
CAS号:
13401-56-4
分子量:
122.59
EC號碼:
236-488-9
MDL號碼:
MFCD00004684
分類程式碼代碼:
12352100
PubChem物質ID:
24851378
NACRES:
NA.22

化驗

99%

折射率

n20/D 1.45 (lit.)

bp

87 °C/35 mmHg (lit.)

mp

34-36 °C (lit.)

SMILES 字串

CC(C)(CO)CCl

InChI

1S/C5H11ClO/c1-5(2,3-6)4-7/h7H,3-4H2,1-2H3

InChI 密鑰

CAZPRAORHCOIHC-UHFFFAOYSA-N

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相关类别

一般說明

3-Chloro-2,2-dimethyl-1-propanol undergoes oxidation with pyridinium chlorochromate to yield 3-chloro-2,2-dimethylpropanal which spontaneously trimerizes to s-trioxane.

應用

3-Chloro-2,2-dimethyl-1-propanol has been used in combinatorial preparation of new aroma-impact compounds such as polyfunctional thiols.

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

159.8 °F - closed cup

閃點（°C）

71 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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2, 4, 6-Tri (2'-chloro-1', 1'-dimethylethyl)-s-trioxane: Synthesis, Spectroscopy and Crystal Structure.
Tarbutton GL and Valente EJ.
Journal of Chemical Crystallography, 40(2), 126-129 (2010)
Catherine Vermeulen et al.
Combinatorial chemistry & high throughput screening, 9(8), 583-590 (2006-10-05)
Combinatorial chemistry was shown to be an efficient tool for the preparation of new aroma-impact compounds. In this case, polyfunctional thiols were synthesized quickly using halide reagents or Bunte salt intermediates. They were separated by gas chromatography and then characterized
Xin Min et al.
Royal Society open science, 5(5), 180156-180156 (2018-06-13)
A novel alkyl lithium-based initiator with relatively large steric hindrance, tert-butyldimethylsiloxydimethylpropyl lithium (TBDMSODPrLi), was designed and synthesized. By using TBDMSODPrLi, hydroxyl-terminated polybutadiene (HTPB) was prepared via anionic polymerization. The macromolecular structure of HTPB was characterized and verified by FTIR and

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