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Merck

185760

Sigma-Aldrich

邻氯硝基苯

99%

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About This Item

线性分子式:
ClC6H4NO2
CAS号:
分子量:
157.55
Beilstein:
509273
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

5.4 (vs air)

蒸汽壓力

0.04 mmHg ( 25 °C)

化驗

99%

形狀

solid

自燃溫度

500 °F

expl. lim.

8.7 %

bp

246 °C (lit.)

mp

31-33 °C (lit.)

溶解度

alcohol: soluble
benzene: soluble
diethyl ether: soluble
water: insoluble

密度

1.348 g/mL at 25 °C (lit.)

SMILES 字串

[O-][N+](=O)c1ccccc1Cl

InChI

1S/C6H4ClNO2/c7-5-3-1-2-4-6(5)8(9)10/h1-4H

InChI 密鑰

BFCFYVKQTRLZHA-UHFFFAOYSA-N

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一般說明

通过使用5%铂碳与甲酸铵或甲酸作为氢供体,将氯硝基苯还原成邻氯苯胺。H-八面沸石-720(沸石)强烈催化邻氯硝基苯与五氧化二氮在二氯甲烷中的反应

應用

邻氯硝基苯用于合成 1-羟基苯并三唑衍生物

象形圖

Skull and crossbones

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Oral

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

258.8 °F - closed cup

閃點(°C)

126 °C - closed cup

個人防護裝備

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Catalytic transfer hydrogenation of aromatic nitro compounds by employing ammonium formate and 5% platinum on carbon.
Gowda DC and Mahesh B.
Synthetic Communications, 30(20), 3639-3644 (2000)
Spectrophotometric Determination of pKa's of 1-Hydroxybenzotriazole and Oxime Derivatives in 95% Acetonitrile-Water.
Fathalla MF and Khattab SN.
J. Chem. Soc. Pak., 33(3), 324-324 (2011)
Zeolite catalysis of aromatic nitrations with dinitrogen pentoxide.
Claridge RP, et al.
J. Chem. Soc. Perkin Trans. II, 9, 1815-1818 (1999)
Hong Liu et al.
Applied and environmental microbiology, 77(13), 4547-4552 (2011-05-24)
Pseudomonas stutzeri ZWLR2-1 utilizes 2-chloronitrobenzene (2CNB) as a sole source of carbon, nitrogen, and energy. To identify genes involved in this pathway, a 16.2-kb DNA fragment containing putative 2CNB dioxygenase genes was cloned and sequenced. Of the products from the
Zhaobing Guo et al.
Water research, 39(6), 1174-1182 (2005-03-16)
The selective adsorption of p-chloronitrobenzene (p-CNB) using zeolite as the adsorbent from an aqueous mixture containing p-CNB and o-chloronitrobenzene (o-CNB) was investigated. The maximum adsorption amounts of p-CNB in HZSM-5 zeolite were found to be approximately 4 molecules per unit

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